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 Multiple Choice QuestionsLong Answer Type

111. Define vapour pressure of a liquid. What happens to the vapour pressure of a liquid when (a) a volatile solute dissolves in it and (b) a non-volatile solute dissolves in it?
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 Multiple Choice QuestionsShort Answer Type

112. What is osmotic pressure? How is it dependent on the number of moles of a solute?
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113. State Raoult’s law. If AT is the elevation of boiling point of a solvent and m is the number of moles of solute per kg of solvent, what is the realationship between T and m?
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114.

(a) What are non-ideal solution?
(b) What role does the molecular interaction play in deciding the vapour pressure of solutions (i) alcohol and kerosene (ii) Chloroform and acetone.

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115. Why do colligative properties of an electrolyte solution of a given concentration are found to be larger than those of a non-electrolyte solution of the same concentration?
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116. Explain the following phenomena:
(i) Hemolysis
(ii) Crenation.


Answer:

(i) Hemolysis: The red blood cells are protected from the external environment by a semipermeable membrane. The red blood cells are placed in a hypotonic solution. Because the hypotonic solution is less concentrated than the interior of the cell, water moves into the cell. The cell swells and eventually burst, releasing hemoglobin and other molecules. This process is called hemolysis.

(ii) Crenation: When a bacterial cell is placed in a hypertonic (high concentration) sugar solution, the intracellular water tends to move out of the bacterial cell to be more concentrated solution by osmosis. This causes the cell to shrink and eventually, to stop functioning. This process is called crenation.

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117. Why do we observe abnormal molecular masses?
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118. How does osmotic pressure depend on molality of the solution?
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 Multiple Choice QuestionsLong Answer Type

119. The molar mass of acetic acid determined from the measurement of a colligative property is greater than its formula molar mass. Explain why?
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 Multiple Choice QuestionsShort Answer Type

120. Explain why solvent-solvent, solute-solute and solute-solvent interactions are important in determining the extent to which a solute dissolves in a solvent.
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