Vapour pressures of pure acetone and chloroform at 328 k are 741.8 nm Hg and 632.8 mm Hg respectively. Assuming that they form ideal solution over the entire range of composition, plot Ptotal , Pchlroform and Pacelone as a function of Xactone. The experimental date observed for different composition of mixture is:
100 x xacetone |
0 |
11.8 |
23.8 |
36.0 |
50.8 |
58.2 |
64.5 |
72.1 |
Pacetone / mm Hg
|
0 |
54.9 |
110.1 |
202.4 |
327.7 |
405.9 |
454.1 |
521.1 |
Pchloroform/ mm Hg |
632.8 |
548.1 |
469.4 |
359.7 |
257.7 |
193.6 |
161.2 |
120.7 |
Plot this data also on the same graph paper, indicate whether it has positive deviation or negative deviation from the ideal solution.
Consider 100 g of 10% solution of glucose whose conc. is 10% W / W.
Mass of solution = 100 g
Mass of glucose = 10 g
Mass of solvent = 100 – 10 = 90 g
Molar mass of glucose,
C6H12O6 = 6 x 12 + 12 x 1 + 6 x 16
= 72 + 12 + 96 = 180 g / mol
Molality =
Moles of
Moles of glucose,
Mole fraction of glucose,
Mole fraction of water
Density of sol = 1.2 g mol L
Therefore, volume of solution
Molarity =