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 Multiple Choice QuestionsLong Answer Type

131. How many mL of 0.1 M HC1 are required to react completely with 1 g mixture of Na2COand NaHCO3 containing equimolar amounts of both?
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132. A solution is obtained by mixing 300 g of 25% solution and 400 g of 40% solution by mass. Calculate the mass percentage of the resulting solution.


Mass of solute in 300 g of solution of 25% conc.
= 25100×300 = 75 g
Mass of solvent in 300 g of solution
= 300 – 75 = 225 g Moles of solute in 400 g of solution of 40% conc.
= 40100×400 = 160 g
Mass of solvent in 400 g of solution
= 400 – 160 = 240 g Total mass of the solute
= 75 + 160 = 235 g Total mass of solvent
= 225 g + 240 g = 465 g Total mass of solution
= 300 + 400 = 700 g Therefore, composition of solute in solution after mixing = 235700×100 = 33.57%
Percentage composition of solvent in solution after mixing
= 465700×100 = 66.43%

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133. An antifreeze solution is prepared from 222.6 g of ethylene glycol (C2H6O2) and 200 g of water. Calculate the molality of the solution. If the density of the solution is 1.072 g mL–1, then what shall be the molarity of the solution?
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134. A sample of drinking water was found to be severely contaminated with chloroform (CHCl3), supposed to be a carcinogen. The level of contamination was 15 ppm (by mass):
(i) express this in percent by mass
(ii) determine the molality of chloroform in the water sample.
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 Multiple Choice QuestionsShort Answer Type

135. The partial pressure of ethane over a solution containing 6.56 x 10–3 g of ethane is 1 bar. If the solution contains 5.00 x 10–2 g of ethane, then what shall be the partial pressure of th gas? 
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136. An aqueous solution of 2% non-volatile solute exerts a pressure of 1.004 bar at the normal boiling point of the solvent. What is the molar mass of the solute?
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 Multiple Choice QuestionsLong Answer Type

137. Heptane and octane form an ideal solution. At 373 K, the vapour pressures of the two liquid components are 105.2 kPa and 46.8 kPa respectively. What will be the vapour pressure, in bar of a mixture of 26.0 g of heptane and 35.0 g of octane? 
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138. The vapour pressure of water is 12.3 kPa at 300 K. Calculate vapour pressure of 1 molar solution of a non-volatile solute in it.
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139. Calculate the mass of a non-volatile solute (molecular mass 40 g mol–1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80%.
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 Multiple Choice QuestionsShort Answer Type

140. If the density of some lake water is 1.25 g mL–1 and contains 92 g of Na+ ions per kg of water, calculate the molality of Na+ ions in the lake. 
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