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231. Urea forms an ideal solution in water. Determine the vapour pressure of an aqueous solution contains 10% by mass of urea at 40⁰C. (Vapour pressure of water at 40⁰C = 55.3 mm of Hg)

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232. A solution is made by dissolving 30 g of a non-volatile solute in 90g of water. It has a vapour pressure of 2.8 kPa at 298 K. At 298 K, vapour pressure of pure water is 3.64 kPa. Calculate the molar mass of the solute.

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233. At 300 K, 36 g of glucose present per litre in its solution has an osmotic pressure of 4.98 bar. If osmotic pressure of solution is 1.52 bar at the same temperature, what would be its concentration.

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234.
Calculate the vapour- pressure lowering of water when5.67g of glucose, C₆H₁₂O₆ is dissolved in 25.2 g water at 25⁰C. The vapour pressure of water at 25⁰C is 23.8 mmHg. What is the vapour pressure of the solution?

W_B=5.67g

W_A=25.2g

M_B=180g/mol

M_A=18g/mol

N_B=5.67/180 =0.0315 mol glucose

N_A=25.2/18 =1.40 mol water

$mole fraction of glucose, x_{B} = \frac{0.0315}{1.40 + 0.0315} = 0.022 we know that lowering of V . P = \frac{p^{0} - p}{p^{0}} x_{B} = 23.8 x 0.022 = 0524 mmHg \frac{p^{0} - p}{p^{0}} = x_{B} p = p_{A}^{0} - (p^{0} - p) = 23.8 - 0.524 = 23.3 mm Hg$

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235. A 4% solution of sucrose is isotonic with 3% solution of an unknown organic substance. Calculate the molecular mass of unknown resistance.

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236. Calculate molarity and molality of 13% solution (by weight of sulphuric acid. Its density is 1.020 g cm^–3. (At. mass, H = 1,16, S = 32 amu).

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237.

What will be the boiling point of bromine when 87.25 x 10^-3 g of Sulphur is added to 39g of bromine? Bromine boils at 332.15K [K_bfor Br₂ -5.2K kgmole^-1]

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238.

The freezing point of a solution containing 0.2g of acetic acid in 20.0 g of benzene is lowered by 0.45⁰C. calculate the degree of association of acetic acid in benzene. (K_f for benzene =5.12K kg mol-1)

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239.

Calculate the amount of ice that will separate out on cooling a solution containing 50g of ethylene glycol in 200g water -9.3⁰C (K_f for water =1.86K kf mol^-1).

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