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 Multiple Choice QuestionsMultiple Choice Questions

521.

The solubility of saturated solution of Ag2CrO4 is s mol L-1. What is its solubility product?

  • 4s3

  • s3

  • 2s3

  • 16s2


522.

The number of phase in a colloidal system is

  • 1

  • 2

  • 3

  • 4


523.

Steel is heated to below red heat and then, cooled slowly. The process refers to

  • hardening

  • annealing

  • tempering

  • nitriding


524.

Which does not give a precipitate with AgNO3 solution?

  • [Co(NH3)6]Cl3

  • [Co(NH3)5Cl]Cl2

  • [Co(NH3)4Cl2]Cl

  • [Co(NH3)3Cl3]


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525.

At 25°C, the dissociation constant of a base, BOH, is 1.0 x 10-12. The concentration of
hydroxyl ions in 0.01 M aqueous solution of the base would be

  • 2.0 x 10-6 mo L-1

  • 1.0 x 10-5 mo L-1

  • 1.0 x 10-6 mo L-1

  • 1.0 x 10-7 mo L-1


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526.

What is the correct relationship between the pHs of isomolar solutions of sodium oxide (pH1), sodium sulphide (pH2), sodium selenide (pH3) and sodium telluride (pH4)?

  • pH1 > pH2 pH3 > pH4

  • pH1 < pH2 pH3 < pH4

  • pH1 < pH2 pH3 pH4

  • pH1 > pH2 pH3 > pH4


D.

pH1 > pH2 pH3 > pH4

The correct order of pH of isomolar solutions is

pH1 > pH2 > pH3 > pH4

sodium oxide > sodium sulphide > sodium selenide > sodium telluride.

This is because, in aqueous solution they are hydrolysed as follows:

Na2O + 2H22NaOHBase + H2O

Na2S + 2H22NaOHStrong base + H2SWeak acid  

Na2Se + 2H22NaOHStrong base + H2SeWeak acid

Na2Te + 2H22NaOH Strong base + H2TeWeak acid

Therefore, the order of acidic strength is

H2Te > H2Se > H2S > H2

Since, the pH of basic solution is higher than acidic or least basic solution.


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527.

A solution of urea (mol. mass 56g mol-1) boils at 100.18°C at the atmospheric pressure. If kf and kb for water are 1.86 and 0.512 K kg mol-1 respectively, the above solution will freeze at

  • -6.54°C

  • 6.54°C

  • 0.654°C

  • - 0.654°C


528.

If the solubility of an aqueous solution of Mg(OH)2 , be X mole litre then ksp of Mg(OH)2 is:

  • 4X3

  • 108X5

  • 27X4

  • 9X


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529.

A storage battery contains a solution of H2SO4 38% by weight. At this concentration, the van't Hoff factor is 2.50. At what temperature will the battery contents freeze? (Kf =1.80 mol' kg)

  • 243.92 K

  • 298 K

  • 240.92 K

  • 273 K


530.

The freezing point depression of 0.001 m Kx[Fe(CN)6] is 7.1x 10-3 K. The value of x will be [Given, Kf = 1.86 KKg mol-1 for water].

  • 2

  • 4

  • 3

  • 1


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