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 Multiple Choice QuestionsMultiple Choice Questions

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601.

The freezing point of water is depressed by 0.37°C in a 0.01 molal NaCl solution. The freezing point of 0.02 molal solution of urea is depressed by

  • 0.37°C

  • 0.74°C

  • 0.185°C

  • 0°C


A.

0.37°C

We know, 

tf = i kjm

where, tf = depression in freezing point; i = van't Hoff factor; m = molality and kf = freezing point depression constant.

For 0.01 molal NaCl solution

0.37 = 2 × kf × 0.01

 kf0.372 × 0.01      ...(i)

For 0.02 molal urea solution

tf  = 1 × k× 0.02

 tftf0.02            ...(ii)

tf = 0.37 × 0.022 × 0.01

 tf = 0.37°C


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602.

Chloroform, when kept open, is oxidised to :

  • CO2

  • COCl2

  • CO2, Cl2

  • None of these


603.

Blood cells will remain as such in:

  • hypertonic solution

  • hypotonic solution

  • isotonic solution

  • none of the above


604.

The mixture that forms maximum boiling azeotrope is:

  • Ethanol + Water

  • Acetone + Carbon disulphide

  • Heptane + Octane

  • Water + Nitric acid


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605.

For an ideal solution, the correct option is :

  • Δmix V ≠  0 at constant T and P

  • Δmix H =  0 at constant T and P

  • Δmix G =  0 at constant T and P

  • Δmix S = 0 at constant T and P


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