Two organic compounds (A) and (B) both containing only carbon and

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 Multiple Choice QuestionsMultiple Choice Questions

291.

The number of formula units of calcium fluoride, CaF2 present in 146.4 g of CaF(the molar mass of CaF2is 78.08 g/mol) is

  • 1.129 × 1024 CaF2

  • 1.146 × 1024 CaF2

  • 7.808 × 1024 CaF2

  • 1.877 × 1024 CaF2


292.

The amount of energy released when 20 mL of 0.5 M NaOH are mixed with 100 mL of 0.1 M HCl is x kJ. The heat of neutralisation is (in kJ mol-1).

  • -100x

  • -50x

  • +100x

  • +50x


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293.

Two organic compounds (A) and (B) both containing only carbon and hydrogen, on quantitative analysis gave the same percentage composition by weight

C=1213 × 100 % H= 113 × 100%

A decolourises bromine water but B does not. A and B respectively are

  • C2H2 and C6H6

  • C6H6 and C2H2

  • C2H4 and C2H6

  • C2H2 and C2H6


A.

C2H2 and C6H6

(i) Find empirical formula.
(ii) Among hydrocarbons, alkynes and arenes have same empirical formula.
(iii)Among hydrocarbons alkene and alkyne decolourise bromine water but alkane and arenes do not.

Given,   C =1213×100%, H =113× 100%C= 92.3% H= 7.69%C=92.3%12= 7.69 = 7.697.69= 1H= 7.691= 7.69 = 7.697.69= 1

Empirical formula of hydrocarbon is
C1H1= CH
Therefore, A has empirical formula CH and decolourises bromine water.
It is alkyne which is C2H2.
Therefore,  B has empirical formula CH and does not decolourise bromine water.
It is benzene C6H6.


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294.

How many grams of dibasic acid (mol. wt. 200) should be present in 100 mL of the aqueous solution to give 0.1 N?

  • 10 g

  • 20 g

  • 2 g

  • 1 g


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295.

At STP, a container has 1 mole of Ar, 2 moles of CO2, 3 moles of O2, and 4 moles of N2. Without changing the total pressure if one mole of O2 is removed, the partial pressure of O2 is

  • changed by about 16%

  • halved

  • changed by 26%

  • unchanged


296.

In a compound C, H and N are present in 9 : 1 : 3.5 by weight. If molecular weight of the compound is 108, then the molecular formula of the compound is

  • C2H6N2

  • C3H4N

  • C6H8N2

  • C9H12N3


297.

What amount of bromine will be required to convert 2 g of phenol into 2, 4, 6-tribromo phenol?

  • 4.00

  • 6.00

  • 10.22

  • 20.44


298.

What is the amount of urea dissolved per litre, if aqueous solution is isotonic with 10% cane sugar solution (mol. wt. of urea = 60) ?

  • 200 g/L

  • 19.2 g/L

  • 17.54 g/L

  • 16.7 g/L


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299.

The volume of 2 N H2SO4 solution is 0.1 dm3. The volume of its decinormal solution (in dm3) will be

  • 0.1

  • 0.2

  • 2

  • 1.7


300.

The percentage (by weight) of sodium hydroxide in a 1.25 molal NaOH solution is

  • 4.76%

  • 1.25%

  • 5%

  • 40%


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