In acidic medium, the equivalent weight of  K2Cr2O7 ( M

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481.

In acidic medium, the equivalent weight of  K2Cr2O7 ( Mol. wt. = M) is

  • M

  • M/2

  • M/3

  • M/6


D.

M/6

potassium dichromate, K2Cr2O7 is a powerful oxidising agent. In acidic medium, its action can be represented as

K2Cr2+6O7 + 4H2SO4  K2SO4 + Cr2+3(SO4)3 + 4H2O + 3[O]Eq. wt. of K2Cr2O7 =molecular weight of K2Cr2O7 2 × change in oxidation number=M2 ×3 [Two Cr atoms are involved.]Eq. wt. of K2Cr2O7 =M6


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482.

What is the total number of moles of H2SO4 needed to prepare 5.0 L at a 2.0M solution of H2SO4 ?

  • 2.5

  • 5.0

  • 10

  • 20


483.

In stoichiometric defect, the ratio of positive and negative ions as indicated by chemical formula of the compound

  • decreases

  • increases

  • changes by a factor of 2

  • remains same


484.

Density of a 2.05 M solution of acetic acid in water is 1.02 g/mL. The molality of the solution is

  • 2.28 mol kg-1

  • 3.28 mol kg-1

  • 0.44 mol kg-1

  • 1.14 mol kg-1


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485.

Consider the following reaction,

(CH3)3CCl + OH- → (CH3)3C-OH + Cl-

If OHdoes not take part in slow step, the molecularity and order of the reaction are respectively,

  • 2, 2

  • 2, 1

  • 1, 2

  • 1, 1


486.

When one litre one molar sulphuric acid solution is diluted with 5 L water, the normality of the obtained solution is

  • 0.2 N

  • 0.33 N

  • 10 N

  • 5 N


487.

The normality of 10 L volume H2O2 is

  • 0.176

  • 0.88

  • 1.78

  • 3.52


488.

Sodium bicarbonate on heating decomposes to form sodium carbonate, CO2 and water. If 0.2 moles of sodium bicarbonate is completely decomposed, how many moles of sodium carbonate is formed?

  • 0.1

  • 0.2

  • 0.05

  • 0.025


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489.

250 mL of a Na2CO3 solution contains 2.65 g of Na2CO3 10 mL of this solution is added to x mL of water to obtain 0.001 M Na2CO3 solution.The value of x is (molecular weight of Na2CO3 = 106)

  • 1000 mL

  • 990 mL

  • 9990 mL

  • 90 mL


490.

Which of the following represents the smallest quantity?

  • 1230g

  • 1.230 × 10-4 g

  • 1.230 × 10-6 kg

  • 1.230 × 104 µg


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