What is the correct order of spin only magnetic moment (in BM) of

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371.

What is the correct order of spin only magnetic moment (in BM) of Mn2+, Cr2+ and V2+ ?

  • Mn2+ > V2+ > Cr2+

  • V2+ > Cr2+ > Mn2+

  • Mn2+ > Cr2+ > V2+

  • Cr2+ > V2+ > Mn2+ 


C.

Mn2+ > Cr2+ > V2+

Spin only magnetic moments depend upon the number of unpaired electrons, more the number of unpaired electron, greater wtll be the spin only magnetic moment.

25Mn = 1s2, 2s2 2p6, 3s2 3p6 3d5, 4s2

Mn2+ = 1s2, 2s2 2p6, 3s2 3p6 3d5, 4s0

Number of unpaired electrons = 5

24Cr = 1s2, 2s2 2p6, 3s2 3p6 3d5, 4s1

Cr2+ = 1s2, 2s2 2p6, 3s2 3p3d4, 4s0

Number of unpaired electrons = 4

23V = 1s2, 2s2 2p6, 3s2 3p6 3d3, 4s2

V2+ = 1s2, 2s2 2p6, 3s2 3p6 3d3, 4s0

Number of unpaired electrons = 3

So, the correct order of spin only magnetic moment is

Mn2+ > Cr2+ > V2+


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372.

The uncertainties in the velocities of two particles A and B are 0.05 and 0.02 m/s-1 respectively. The mass of B is five times to that of mass A. What is the ratio of uncertainities xAxB in their positions?

  • 2

  • 0.25

  • 4

  • 1


373.

The energy of a photon is 3 × 10-12 ergs. What is its wavelength in nm ?

(h = 6.62 × 10-27 ergs ; c = 3 × 1010 cm/s)

  • 662

  • 1324

  • 66.2

  • 6.62


374.

Which of the following is not correct ?

  • Nuclei of atoms participate in nuclear reactions

  • 20Ca40 and 18Ar40 are isotones

  • 1 amu of mass defect is approximately equal to 931.5 MeV.

  • Uranium (U238) series is known as (4n + 2) series.


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375.

An electronic transition in hydrogen atom results in the formation of Hα line of hydrogen in Lyman series, the energies associated with the electron in each of the orbits involved in the transition (in kcal mol-1) are 

  • -313,6, - 34.84

  • -313.6, - 78.4

  • -78.4,- 34.84

  • -78.4,-19.6


376.

The velocities of two particles A and B are 0.05 and 0.02 ms-1 respectively. The mass of B is five times the mass of A. The ratio of their de-Broglie's wavelength is

  • 2 : 1

  • 1 : 4

  • 1 : 1

  • 4 : 1


377.

For a crystal, the angle of diffraction (2 θ) is 90° and the second order line has a d value of 2.28 Å. The wavelength (in Å) of X-rays used for Bragg's diffraction is

  • 1.612

  • 2.00

  • 2.28

  • 4.00


378.

The wavelength of a spectral line emitted by hydrogen atom in the Lyman series is 1615R cm. What is the value of n2? ( R= Rydberg constant).

  • 2

  • 3

  • 4

  • 1


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379.

The maximum number of sub-levels, orbitals and electrons in N shell of an atom are respectively

  • 4, 12, 32

  • 4, 16, 30

  • 4, 16, 32

  • 4, 32, 64


380.

The wavelengths of electron waves in two orbits is 3 : 5. The ratio of kinetic energy of electrons will be 

  • 25 : 9

  • 5 : 3

  • 9 : 25

  • 3 : 5


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