Splitting of spectrum lines in magnetic field is from Chemistry

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491.

Splitting of spectrum lines in magnetic field is

  • Stark effect

  • Raman effect

  • Zeeman effect

  • Rutherford effect


C.

Zeeman effect

Zeeman effect is the splitting of spectral lines under the influence of magnetic field.

Stark effect is the splitting of spectral lines under the influence of electric field.

Raman effect is when light of frequency v0 is scattered by molecules of a substance which have a vibrational frequency of v1, the scattered light when analysed spectroscopically has lines of frequency v where, 

v = v0 ± v0

Rutherford effect takes place on the bombardment of the atoms by high speed α particles, the centre of the atom scatters the α-particles.


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492.

Decrease in atomic number is not observed during

  • β- emission

  • α- emission

  • positron emission

  • electron capture


493.

According to Bohr's theory, the angular momentum for an electron in 5th orbit is

  • 2.5 h/ π

  • 5 h/ π

  • 25 h/ π

  • π/ 2h


494.

If a species has 16 protons, 18 electrons and 16 neutrons, the symbol (with charge) of species is

  • S-

  • Si2-

  • P3-

  • S2-


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495.

'No two electrons in an atom can have the same set of  quantum numbers.' This principle is known by which one of the following?

  • Zeeman's exclusion principle

  • Stark's exclusion principle

  • Pauli's exclusion principle

  • Hersbach's exclusion principle


496.

Consider the ground state of Cr atom (Z= 24). The numbers of electrons with the azimuthal quantum numbers, = 1 and 2 are respectively

  • 12 and 4

  • 12 and 5

  • 16 and 4

  • 16 and 5


497.

What is the wavelength associated with a tennis ball of mass 103 g and travelling at a velocity of 6.626 ms-1 ?[h = 6.626 x 10-34 Js-1].

  • 10-34 m

  • 10-31 m

  • 6.626 m

  • 6.626 × 10-31 m


498.

What is the energy required to move the electron from ground state of H atom to the first excited state? Given that the ground state energy of H atom is 13.6 eV and that the energy En of an electron in nth orbital of an atom or ion of atomic number Z is given by the equation En= - (13.6Z2 /n2).

  • 13.6 eV

  • 3.4 eV

  • 10.2 eV

  • -10.2 eV


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499.

Which electron orbitals are designated by
(i) n = 2, l = 1, m = 0;
(ii) n = 3, l=2, m = O;
(iii) n=4, l = 2, m=1 and
(iv) n = 5, l=3, m=3 respectively?

  • 2p, 3d, 4d and 5f, respectively

  • 2p, 3d, 4d and 5d, respectively

  • 2p, 3d, 4f and 5f, respectively

  • 2p, 3p, 4d and 5f, respectively


500.

Which one of the following represents the correct ratio of the energy of electron in ground state of H atom to that of the electron in the first excited state of Li+?

  • 4 : 9

  • 9 : 4

  • 1 : 4

  • 4 : 1


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