Which one of the following complexes is an outer orbital complex?

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501.

Which one of the following complexes is an outer orbital complex?

(Atomic number of Mn = 25; Fe = 26; Co = 27 and Ni = 28)

  • [Fe(CN)6]4-

  • [Mn(CN)6]4-

  • [Co(NH3)6]3+

  • [Ni(NH3)6]2+


D.

[Ni(NH3)6]2+

Among the given options, option d is a complex of an outer orbital.

NH3 is a strong ligand.

In this case, NH3 is a strong ligand but electrons remain unpaired since only one orbital is left vacant in 3d. Thus,


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502.

Which of the following has the largest number of atoms?

  • 0.5 gm atom of Cu

  • 0.635 gm of Cu

  • 0.25 moles of Cu atoms

  • 1 gm of Cu


503.

Which of the following will violate Pauli's exclusion principle?

  • Both (a) and (b)

  • None of the above


504.

The ratio of the difference in energy between the first and second Bohr orbit to that between the second and third Bohr orbit is

  • 12

  • 127

  • 49

  • 275


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505.

Which pair of elements has same chemical properties?

  • 13, 22

  • 3, 11

  • 4, 24

  • 2, 4


506.

The wave number of hydrogen atom in Lyman series is 82200 cm-1. The electron goes from

  • n3 → n2

  • n2 → n1

  • n4 → n3

  • None of these


507.

The radius of which of the following orbit is same as that of the first Bohr's orbit of hydrogen atom?

  • Li2+ (n = 2)

  • Li2+ (n = 3)

  • Be3+ (n = 2)

  • He+ ( n = 2)


508.

Which of the following set of quantum numbers represents the highest energy of an atom?

  • n =3, l=2, m=1, s= +1/2

  • n=4, l=0, m=0, s= -1/2

  • n=3, l=0, m=4, s= +1/2

  • n=3, l=1, m=1, s=+1/2


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509.

The number of radial nodes present in 3p orbital is

  • 0

  • 1

  • 2

  • 3


510.

The radiation with maximum frequency is

  • X-ray

  • radio waves

  • UV rays

  • IR rays


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