Assertion : C- O bond in metal carbonyl is long.Reason : There is

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 Multiple Choice QuestionsMultiple Choice Questions

631.

A metal surface is exposed to solar radiations :

  • the emitted electrons have energy less than a maximum value of energy depending upon frequency of incident radiations

  • the emitted electrons have energy less than maximum value of energy depending upon intensity of incident radiations

  • the emitted electrons have zero energy

  • the emitted electrons have energy equal to energy of photons of incident light


632.

Which of the following transitions have minimum wavelengths ?

  • n4  n1

  • n2  n1

  • n4  n2

  • n3  n1


633.

Orbital is :

  • circular path around the nucleus in which the electrons revolves

  • space around the nucleus where the probability of finding the electron is maximum

  • amplitude of electron wave

  • none of the above


634.

Which of the following sequence is correct as per Aufbau principle ?

  • 3s < 3d < 4s < 4p

  • ls < 2p < 4s < 3d

  • 2s < 5s < 4p < 5d

  • 2s < 5s < 4p < 5f


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635.

A radioactive nucleus will not emit :

  • alpha and beta rays simultaneously

  • beta and gamma rays simultaneously

  • gamma and alpha rays

  • gamma rays only


636.

X-rays are emitted during

  • α, n reaction

  • K-capture

  • n, α-reaction

  • β- emission 


637.

72X180 2α β γ zXA , Z and A are :

  • 69 , 172

  • 172 , 69

  • 180 , 70

  • 182 , 68


638.

Assertion : The quantized energy of an electron is largely determined by its principal quantum number.

Reason : The principal quantum number n is a measure of the most probable distance of finding the electron around the nucleus.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


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639.

Assertion : C- O bond in metal carbonyl is long.

Reason : There is delocalisation of electrons from filled d orbitals into the empty orbitals on the CO ligands.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false

  • If both assertion and reason are false.


A.

If both assertion and reason are true and reason is the correct explanation of assertion.

C-O bond in metal carbonyl is long as ligated CO has lower bond order. The lower B.O. is clue to the transfer of metal electrons into the π*orbitals of ligated CO.


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640.

Isotopic pair is :

  • 20X4021X40

  • 20X40 , 20X41

  • 40X2041X20

  • None


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