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 Multiple Choice QuestionsLong Answer Type

101. What is an adsorption isotherm ? Describe Freundlich adsorption isotherm.
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 Multiple Choice QuestionsShort Answer Type

102. What do you understand by activation of adsorbent? How is it achieved?
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103. What role does adsorption play in heterogeneous catalysis?
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104. Why is adsorption always exothermic?
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 Multiple Choice QuestionsLong Answer Type

105. How are the colloidal solutions classified on the basis of physical states of the dispersed phase and dispersion medium? 
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106. Discuss the effect of pressure and temperature on the adsorption of gases on solids. 
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107. What are lyophilic and lyophobic sols? Give one example of each type. Why are hydrophobic sols easily coagulated?
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108. What is the difference between multimolecular and macromolecular colloids? Give one example of each. How are these two types of colloids different from these two types of colloids? 


Answer:

Multimolecular colloids:
(i) Consist of aggregates of atoms or molecules with diameter less than 10–9 m.
(ii) The atom or molecules are held together by weak Vander Waals forces.

Macromolecular colloids:
(i) Are themselves large. Many behave as macromolecular colloids because of their large molecular masses.
(ii) Since the molecules are flexible, they can take on various shapes.

Associated colloids:

(i) Behave as true solution in smaller concentrations and colloids at higher concentrations.

(ii) Sodium stearate behaves as strong electrolyte in dilute solutions and shows the properties of sodium and stearate ions form aggregates and behave as colloids. The aggregates formed are called micelles which revert to individual ions on dilution.
Example of multi-molecular colloid: Gold sol, Sulphur sol.
Example of macro-molecular colloid:Cellulose, Starch.

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109. What are enzymes? Write in brief the mechanism of enzyme catalysis.
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110. How are colloids classified on the basis of
(i) physical states of components
(ii) nature of dispersed phase and
(iii) interaction between dispersed phase and dispersion medium?
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