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 Multiple Choice QuestionsShort Answer Type

151. Give reasons for the following:
Copper(I) has d10 configuration while copper(ll) hs d9 configuration, still copper(II) is more stable in aqueous solution than copper(I).
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152. Give reasons for the following:
The second and third transition series elements have almost similar atomic radii.
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153.

Calculate the number of unpaired electrons in following gaseous ions: Mn3+, Cr3+, V3+ and Ti3+, which one of these is the most stable in aqueous solution?

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154.

Give example and suggest reasons for the following features of the transition metal chemistry:
The lowest oxide of transition metal is basic, the highest is amphoteric/acidic.

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155.

Give example and suggest reasons for the following features of the transition metal chemistry:
A transition metal exhibits highest oxidation state in oxides and fluroides.


The oxidation state of an element is related to the number of electrons that an atom loses, gains, or appears to use when joining with another atom in compounds. It also determines the ability of an atom to oxidize (to lose electrons) or to reduce (to gain electrons) other atoms or species. Oxidation results in an increase in the oxidation state. Reduction results in a decrease in the oxidation state.  If an atom is reduced, it has a higher number of valence shell electrons, and therefore a higher oxidation state, and is a strong oxidant. For example, oxygen (O) and fluorine (F) are very strong oxidants.Both oxide and fluoride ions are highly electronegative and have a very small size. Due to these properties, they are able to oxidize the metal to its highest oxidation state.

 

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156.

Give example and suggest reasons for the following features of the transition metal chemistry:
The highest oxidation state is exhibited in oxoanions of a metal.

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157.

Indicate the steps in the preparation of  K2Cr2Ofrom chromite ore.

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158.

Indicate the steps in the preparation of KMnOfrom pyrolusite ore.

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159. What are alloys? Name an important alloy which contains some of the lanthanoid metals. Mention its uses. 
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160. What are inner transition elements? Decide which of the following atomic numbers are the atomic numbers of the inner transition elements: 29, 59, 74, 95, 102, 104
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