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 Multiple Choice QuestionsShort Answer Type

151. Give reasons for the following:
Copper(I) has d10 configuration while copper(ll) hs d9 configuration, still copper(II) is more stable in aqueous solution than copper(I).
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152. Give reasons for the following:
The second and third transition series elements have almost similar atomic radii.
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153.

Calculate the number of unpaired electrons in following gaseous ions: Mn3+, Cr3+, V3+ and Ti3+, which one of these is the most stable in aqueous solution?

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154.

Give example and suggest reasons for the following features of the transition metal chemistry:
The lowest oxide of transition metal is basic, the highest is amphoteric/acidic.

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155.

Give example and suggest reasons for the following features of the transition metal chemistry:
A transition metal exhibits highest oxidation state in oxides and fluroides.

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156.

Give example and suggest reasons for the following features of the transition metal chemistry:
The highest oxidation state is exhibited in oxoanions of a metal.


The highest oxidation state of transition element is seen in oxides and these oxides are acidic in nature. These acidic oxides dissolve in base and form oxoanions of transition metal. Thus oxoanions of transition element show highest oxidation state of transition metal. Examples are:
The highest oxidation state of Cr is +6 and it is observed that in its oxo-anion, CrO42–(chromate ion) and Cr2O72– (dichromate ion).
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157.

Indicate the steps in the preparation of  K2Cr2Ofrom chromite ore.

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158.

Indicate the steps in the preparation of KMnOfrom pyrolusite ore.

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159. What are alloys? Name an important alloy which contains some of the lanthanoid metals. Mention its uses. 
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160. What are inner transition elements? Decide which of the following atomic numbers are the atomic numbers of the inner transition elements: 29, 59, 74, 95, 102, 104
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