Lanthanides |
Actinides |
1. Lanthanides show +3 oxidation state only except in few cases where it is +2 or +4. Oxidation states exhibited by lanthanides is never more than +4. |
1. Actinides show higher oxidation states such as +4, +5, +6, +7 also in addition to +3. |
2. Paramagnetic properties of lanthanides can be easily explained.
|
2. Paramagnetic properties are difficult to interpret.
|
3. Lanthanides do not form complexes.
|
3. They have a greater tendency to complex formation. Even -complexes are formed by actinides.
|
4. Lanthanide compounds are less basic.
|
4. Compounds of these are sufficiently basic.
|
5. Lanthanides do not form oxo ions.
|
5. These in higher oxidation states form oxo ions. |
6. Except promethium, these are ion-radio-active. |
6. Such as UO22+, NbO+, PuO,2+etc. |
Account for the following facts:
The reduction of a metal oxide is easier if the metal formed is in liquid state at the temperature of reduction.
Account for the following facts:
The reduction of Cr2O3 with Al is the thermo-dynamically feasible, yet it does not occur at room temperature.