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 Multiple Choice QuestionsMultiple Choice Questions

411. '925 fine silver' means an alloy of
  • 7.5% Ag and 92.5% Cu

  • 92.5% Ag and 7.5% Cu

  • 80% Ag and 20% Cu

  • 90% Ag and 10% Cu


412.

Assertion (A): Cu2+ and Cd2+ are separated by first adding KCN solution and then passing H-S gas.
Reason (R): KCN reduces Cu2+ to Cu+ and forms a complex with it.
The correct answer is

  • Both (A) and (R) are true and (R) is the correct explanation of (A)

  • Both (A) and (R) are true but (R) is not the correct explanation of (A)

  • (A) is true but (R) is not true

  • (A) is not true but (R) is true


413.

The effective atomic number of cobalt in the complex [Co(NH3)6]+ is

  • 36

  • 24

  • 33

  • 30


414.

The correct formula of the complex tetraammineaquachlorocobalt (III) chloride is

  • [Cl(H2O)(NH3)4Co]Cl

  • [CoCl(H2O)(NH3)4]Cl

  • [Co(NH3)4(H2O)Cl]Cl

  • [CoCl(H2O)(NH3)4]Cl2


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415.

Across the lanthanide series, the basicity of the lanthanide hydroxides

  • increases

  • decreases

  • first increases and then decreases

  • first decreases and then increases


416.

Sterling silver is

  • AgNO3

  • Ag2S

  • Alloy of 80% Ag+ 20% Cu

  • AgCl


417.

Identify the statement which is not correct regarding CuSO4

  • It react with KI to give iodine

  • It react with KCl to give Cu2Cl2

  • It react with NaOH and glucose to give Cu2O.

  • It gives CuO on strongly heating in air.


418.

Transition metals usually exhibit highest oxidation states in their

  • chlorides

  • fluorides

  • bromides

  • iodides


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419.

Which one of the following sets correctly represents the increase in the paramagnetic property of the ions?

  • Cu2+ > V 2+ > Cr2+ > Mn2+

  • Cu2+ < Cr2+  < V 2+ < Mn2+

  • Cu2+ < V 2+ < Cr2+ < Mn2+

  • V 2+ < Cu2+  < Cr2+ < Mn2+


C.

Cu2+ < V 2+ < Cr2+ < Mn2+

Paramagnetic property depends upon the number of unpaired electrons. Higher the number of unpaired electrons, higher the paramagnetic property will be

Cu2+ =  [Ar] 3d9 , no. of unpaired electrons = 1 

V 2+ = [Ar] 3d3, no. of unpaired electrons = 3

Cr2+ = [Ar] 3d4, no. of unpaired electrons = 4

Mn2+ = [Ar] 3d5, no.of unpaired electrons = 5

Hence, correct order is

Cu2+ < V 2+ < Cr2+ < Mn2+


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420.

Which of the following is not a characteristic of transition elements?

  • Variable oxidation states

  • Formation of coloured compounds

  • Formation of interstitial compounds

  • Natural radioactivity


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