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 Multiple Choice QuestionsMultiple Choice Questions

441.

Identify the metal that forms colourless compounds.

  • Iron (Z = 26)

  • Chromium (Z = 24)

  • Vanadium (Z=23)

  • Scandium (Z =21)


442.

Consider the following statements.

I. La(OH)3 is the least basic among hydroxides of lanthanides.

II. Zr4+ and Hf4+ possess almost the same ionic radii.

III. Ce4+ can act as an oxidising agent.

Which of the above is/are true?

  • I and III

  • II and III

  • II only

  • I and II


443.

Pick out the correct statement(s).

1. Manganese exhibits +7 oxidation state
2. Zinc forms coloured ions
3. [CoF6]3- is diamagnetic
4. Sc forms +4 oxidation state
5. Zn exhibits only +2 oxidation state

  • 1 and 2

  • 1 and 5

  • 2 and 4

  • 3 and 4


444.

The maximum oxidation state exhibited by actinide ions is

  • +5

  • +4

  • +7

  • +8


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445.

Pick out the correct statements from the following

1.Cobalt (III) is more stable in octahedral complexes.

2. Zinc forms coloured ions or complexes.

3. Most of the d-block elements and their compounds are ferromagnetic.

4. Osmium shows (VIII) oxidation state.

5. Cobalt (II) is more stable in octahedral complex.

  • 1 and 2

  • 1 and 3

  • 2 and 4

  • 1 and 4


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446.

Which of the following statements is not correct?

  • The complexes [NiCl4]2- and [Ni(CN)4]2- differ in the state of hybridization of nickel

  • The complexes [NiCl4]2- and [Ni(CN)4]2- differ in the magnetic properties

  • The complexes [NiCl4]2- and [Ni(CN)4]2- differ in geometry

  • The complexes [NiCl4]2- and [Ni(CN)4]2- differ in primary valencies of nickel


D.

The complexes [NiCl4]2- and [Ni(CN)4]2- differ in primary valencies of nickel

The primary valencies of Ni, in the complexes [Ni(Cl4)]2- and [Ni(CN4)]2- is same, i.e., (+II).

Primary valencies are those valencies in which a metal exhibits in the formation of its simple salt, these are non directional. It is also referred as oxidation state of central metal atom. 


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447.

Which one of the following pairs of elements is called 'chemical twins' because of their very similar chemical properties ?

  • Mn and W

  • Mo and Tc

  • Fe and Re

  • Hf and Zr


448.

Effective magnetic rnoment of Sc3+ ion is :

  • 1.73

  • 0

  • 5.92

  • 2.83


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449.

Potassium permanganate acts as an oxidant in alkaline and acidic media. The final products formed from KMnO4 in the two conditions are respectively

  • MnO2- and Mn3+

  • Mn3+ and Mn2+

  • Mn2+ and Mn3+

  • MnO2 and Mn2+


450.

The catalytic activity of the transition metals and their compounds is described to :

  • their chemical reactivity 

  • their magnetic behaviour

  • their unfilled d-orbitals

  • their ability to adopt multiple oxidation states and their complexing ability


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