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 Multiple Choice QuestionsMultiple Choice Questions

461.

KO2 exhibits paramagnetic behaviour. This is due to the paramagnetic nature of

  • KO-

  • K+

  • O2

  • O-2


462.

Which one of the following ions has same number of unpaired electrons as those present in V+ ion?

  • Fe3+

  • Ni2+

  • Mn2+

  • Cr3+


463.

Which of the following characteristics of the transition metals is associated with their catalytic activity?

  • Colour of hydrated ions

  • Diamagnetic behaviour

  • Paramagnetic behaviour

  • Variable oxidation states


464.

What are X and Y in the following reactions?

MnO4- + I- H+ XMnO4- + I- H2O Y

  • I2, IO4-

  • I2, IO3-

  • IO3-, IO3-

  •  IO3-,I2,


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465.

Which of the following transition metals shows the highest oxidation state?

  • Sc

  • Ti

  • Mn

  • Zn


466.

Which of the ions having following electronic structure would have maximum magnetic moment?

  • 1s2, 2s2, 2p6,3s2,3p6,3d3

  • 1s2, 2s2, 2p6,3s2,3p6,3d5

  • 1s2, 2s2, 2p6,3s2,3p6,3d7

  • 1s2, 2s2, 2p6,3s2,3p6,3d9


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467.

Which of the following ions forms most stable complex compound?

  • Cu2+

  • Ni2+

  • Fe2+

  • Mn2+


A.

Cu2+

The transition elements form complexes because of the following reasons-

(i) They have small size.

(ii) They have large effective nuclear charge.

(iii) They have vacant d-orbitals so that these orbitals can accept lone pairs of electrons donated by the ligands. 

Cu2+ has smallest size and highest nuclear charge among the given species. Hence, it forms the most stable complex compound.


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468.

Pb2+, Cu2+, Zn2+ and Ni2+ ions are present in a given acidic solution. On passing hydrogen sulphide gas through this solution the available precipitate will contain

  • PbS and NiS

  • PbS and CuS

  • CuS and ZnS

  • CuS and NiS


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469.

To an acid solution of an anion a few drops of KMnO4 solution are added. Which of the following, if present will not decolourise the KMnO4 soltuion?

  • NO2-

  • S2-

  • Cl-

  • CO32-


470.

AgNO3 gives red colour with

  • NaCl

  • NaBr

  • NaI

  • K2CrO4


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