Transitional elements are mostly
diamagnetic
paramagnetic
neither diamagnaetic nor paramagnetic
diamagentic and paramagnetic both
Atomic radii of Ti, Zr and Hf vary
Ti>Zr> Hf
Ti<Zr< Hf
Ti< Hf<Zr
Ti<Zr=HF
D.
Ti<Zr=HF
Ti, Zr and Hf belong to IV B group of Periodic Table and in a group atomic radii increases on moving down. However, the transition metals of 4d-series have nearly the same radii as metals of Sd-series.
Hence, the order of atomic radii is
Ti < Zr = Hf
Due to nearly equal atomic radii, Zr and Hf are called chemical twins.
Which of the following radicals will not be precipitated by passing H2S in concentrated acid solution?
Copper
Antimony
Arsenic
Cadmium
In which of the following solvents, AgBr will have the highest solubility?
10-3 M NaBr
10-3 M NH4OH
Pure water
10-3 M HBr
Which transition element of the following outermost electronic configuration shows the highest oxidation state?
3d3, 4s2
3d5, 4s1
3d5, 4s2
3d6, 4s2
Which of the following two ions have the same number of unpaired electrons ?
(1) Mn3+ (2) Fe3+ (3) Cr3+ (4) Co3+
(2) and (3)
(3) and (4)
(1) and (2)
(1) and (4)
The lanthanoid contraction is responsible for the fact that
Zn and Y have about same radius
Zr and Nb have similar oxidation states
Zr and Hf have about the same radius
Zr and Zn have the same oxidation state
The equivalent weight of MnSO4, is equal to its molecular weight when it is converted to
Mn2O3
MnO2
MnO
MnO
The mineral from which potassium permanganate is manufactured
manganite, Mn2O3.H2O
pyrolusite, MnO2
Both (a) and (b)
None of the above