Which one of the following transition metal ion is coloured?
Cu+
Zn2+
Sc3+
V4+
D.
V4+
Among the given options, V4+ is coloured.
The electronic configuration of V4+ is [Ar]3d1 4s0. It has one unpaired electron in its d-subshell. On exposure to visible light, the excitation of unpaired d-electrons takes place from lower to higher energy d-sublevels. The d-d excitation during complex formation permits the absorbance of required wavelength and rest light is transmitted out. Thus, transition metals or metal ions having unpaired d-electrons appears coloured.
The aqueous ferrous ion is green, ferric ion is pale yellow. The aqueous chromic ion is green, hence the colour of chromate ion must be
orange
colourless
yellow
red
belongs to IIIB group of the Periodic.When it loses one α -particle, the new element will belong to the group.
I B
V B
I A
III B
Which set of elements have nearly the same atomic radii ?
F, Cl, Br, I
Na, K, Rb, Cs
Fe, Co, Ni, Cu
Li, Be, B, C
When MnO2 is heated with PbO2 and conc. HNO3 pink colour is obtained due to formation of
KMnO4
HMnO4
Pb(MnO4)2
PbMnO2
In nitroprusside ion, the iron and NO as Fe2+ and NO+ rather than Fe3+ and NO. These forms can be differentiated by
estimating the concentration of iron
measuring the concentration of CN-
measuring the solid state magnetic moment
thermally decomposing the compound
Which of the following compounds gives PELIGOT's salt with chromyl chloride?
Borax
Oxone
Sylvine
Trona