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 Multiple Choice QuestionsMultiple Choice Questions

501.

Which one of the following transition metal ion is coloured?

  • Cu+

  • Zn2+

  • Sc3+

  • V4+


502.

Correct order of paramagnetism is

  • Mn>Cr> Zn

  • Fe> Zn> Cr

  • Cr> Fe> Zn

  • Zn >Mn> Fe


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503.

The aqueous ferrous ion is green, ferric ion is pale yellow. The aqueous chromic ion is green, hence the colour of chromate ion must be

  • orange

  • colourless

  • yellow

  • red


C.

yellow

Most of the compounds of transition metals are coloured in solid as well as solution state. Colour in transition metal ions is usually due to electron transition within the d-shell. Intensely coloured ions with the metal in its highest oxidaton state (e.g., Mn7+, Cr6+, Fe6+) derive the colour from electrons transitions between the metal and the oxygen atom.

Iron:

(i) Fe2+ is green.

(ii) Fe3+ is pale yellow in colour.

Chromium : The colour of chromic ion, i.e., Cr3+ depends around the ligand around the ion. Aqueous solution contains the violet octahedral hexaaquachromium (III) ion, but when some of the water ligands are replaced by other species, such Cr3+ ions are green.

[Cr(H2O)6]3+Violent, octahedral (aq) + 3OH- (aq) [Cr(OH)3(H2O)6] (s)Green, octahedral + 3H2O (l)

In chromate ion (CrO42-), Cr occurs in +6 oxidation state and it is yellow in colour.


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504.

In acidic medium, the equivalent weight of  K2Cr2O7 (Mol. wt. = M) is

  • M

  • M/2

  • M/3

  • M/6


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505.

U92235 belongs to IIIB group of the Periodic.When it loses one α -particle, the new element will belong to the group.

  • I B

  • V B

  • I A

  • III B


506.

Which set of elements have nearly the same atomic radii ?

  • F, Cl, Br, I

  • Na, K, Rb, Cs

  • Fe, Co, Ni, Cu

  • Li, Be, B, C


507.

When MnO2 is heated with PbO2 and conc. HNO3 pink colour is obtained due to formation of

  • KMnO4

  • HMnO4

  • Pb(MnO4)2

  • PbMnO2


508.

Which of the following ions has the highest magnetic moment ?

  • Zn2+

  • Ti3+

  • Sc3+

  • Mn2+


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509.

In nitroprusside ion, the iron and NO as Fe2+ and NO+ rather than Fe3+ and NO. These forms can be differentiated by

  • estimating the concentration of iron

  • measuring the concentration of CN-

  • measuring the solid state magnetic moment

  • thermally decomposing the compound


510.

Which of the following compounds gives PELIGOT's salt with chromyl chloride?

  • Borax

  • Oxone

  • Sylvine

  • Trona


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