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581.

Assuming complete ionisation, same moles of which of the following compounds will require the least amount of acidified KMnO4 for complete oxidation?

  • FeSO4

  • FeSO3

  • FeC2O4

  • FeC2O4


A.

FeSO4

FeSO4 will require the least amount of acidified KMnO4 for complete oxidation.

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582.

Which of the statements given below is incorrect?

  • Cl2O7 is an anhydride of perchloric acid

  • O3molecule is bent

  • ONF is isoelectronic with NO2

  • ONF is isoelectronic with NO2

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583.

Which one of the following compounds is a peroxide? 

  • KO2

  • BaO2

  • MnO2

  • MnO2

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584.

Which of the following ions will exhibit colour in aqueous solutions?

  • La3+ (Z = 57)

  • Ti3+ (Z = 22)

  • Lu3+

  • Lu3+

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585.

Which of the following oxidation states is the most common among the lanthanoids

  • 4

  • 2

  • 5

  • 5

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586.

The Number of moles of KMnO4  that will be needed to react with one mole of sulphite ion in acidic solution is:

  • 3/5

  • 4/5

  • 2/5

  • 1


587.

Identify the incorrect statement among the following:

  • There is a decrease in the radii of the atoms or ions as one proceeds from La to Lu.

  • Lanthanoid contraction is the accumulation of successive shrinkages

  • As a result of lanthanoid contraction, the properties of 4d series of the transition elements have no similarities with the 5d series of elements

  • As a result of lanthanoid contraction, the properties of 4d series of the transition elements have no similarities with the 5d series of elements


588.

Which one of the following ions is the most stable in aqueous solution?

  • Cr3+

  • V3+

  • Ti3+

  • Ti3+


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589.

More the number of oxidation states are exhibited by the actinoids than by the lanthanoids. The main reason for this is:

  • more energy difference between 5f and 6d orbitals than that between 4f and 5d orbitals

  • the lesser energy difference between 5f and 6d orbitals than that between 4f and 5d orbitals

  • the greater metallic character of the lanthanoids than that of the corresponding actinoids

  • the greater metallic character of the lanthanoids than that of the corresponding actinoids

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590.

It is because of inability of ns2 electrons of the valence shell to participate in bonding that

  • Sn2+ is reducing while Pb4+ is oxidising

  • Sn2+ is oxidising while Pb4+ is reducing

  • Sn2+ and Pb2+ are both oxidising and reducing

  • Sn2+ and Pb2+ are both oxidising and reducing

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