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 Multiple Choice QuestionsMultiple Choice Questions

611.

For the same transition metal ion, the colour of its compounds will depend upon:

  • temperature of the reaction

  • pressure of the reaction

  • nature of ligands or Lewis bases attached to the metal ion

  • concentration of the ligands


612.

The 3rd transitional series contain elements having atomic numbers from:

  • 21 to 29

  • 21 to 30

  • 20 to 30

  • 21 to 31


613.

The transition metals mostly are

  • paramagnetic

  • diamagnetic

  • both 'a' and 'b'

  • neither diamagnetic nor paramagnetic


614.

Among the oxides, Mn2O7 (I) , V2O3 (II) , V2O5 (III) , CrO (IV) , Cr2O3 (V) the basic oxides are :

  • I and II

  • II and III

  • III and IV

  • II and IV


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615.

The oxygen carrying pigment , oxyhaemocyanin containing two copper ions is diamagnetic , because :

  • the two copper ions are in + 1oxidation state

  • one copper ion is in + 1oxidation state while other is in + 2 oxidation state

  • of the strong antiferromagnetic interactions between two copper ions

  • of the ferromagnetic interactions between the two copper ions


616.

Which is not true statement ?

  • Ions of d-block elements are coloured due to d-d transition

  • Ions of f-block elements are coloured due to f-f transition

  • [Sc(H2O)6]3+ , [Ti(H2O)6]4+ are coloured complexes

  • Cu+ is colourless ion


617.

The reaction between metallic silver and aqueous NaCN forming a soluble complex occurs in the presence of :

  • nitrogen

  • oxygen

  • helium

  • chlorine


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618.

Which one is colourless ?

  • Co2+

  • Ni2+

  • Fe3+

  • Cu+


D.

Cu+

Co2+ , Ni2+ , Fe3+ have 3 , 2 and 5 unpaired electrons respectively , while in cu+ there is no unpaired electron. This is the reason Cu+ is colourless ion.


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619.

In first transition series, which element show maximum oxidation states :

  • Co

  • Mn

  • Cr

  • Fe


620.

The most paramagenetic is :

  • Cr3+

  • Co2+

  • Mn2+

  • Fe2+


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