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 Multiple Choice QuestionsMultiple Choice Questions

681.

Which of the following element does not show variable valency ?

  • Ni

  • Zn

  • Cu

  • Mn


682.

For decolourization of 1 mole of KMnO4, the moles of H2O2 required is

  • 1/2

  • 3/2

  • 5/2

  • 7/2


683.

Lanthanide for which +II and +III oxidation states are common is

  • La

  • Nd

  • Ce

  • Eu


684.

The compound used for gravimetric estimation of copper(II) is

  • Cu2(SCN)2

  • Cu2O

  • Cu2I2

  • Cu2CO3


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685.

Which of the following has highest second  ionization energy?

  • Ni

  • V

  • Cr

  • Mn


686.

Which of the following compound is not coloured?

  • Na2[CuCl4]

  • Na2[CdCl4]

  • K4[Fe(CN)6]

  • K3[Fe(CN)6]


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687.

The electronic configuration of Cu is

  • [Ne] 3s2, 3p6, 3d9, 4s2

  • [Ne] 3s2, 3p6, 3d10, 4s1

  • [Ne] 3s2, 3p6, 3d3, 3d9, 4s2, 4p6

  • [Ne] 3s2, 3p6, 3d5, 4s2, 4p4


B.

[Ne] 3s2, 3p6, 3d10, 4s1

Atomic number of Copper is 29, its electronic configuration is-

Cu29 = 1s2, 2s2, 2p6, 3s2, 3p6, 3d10, 4s1

Since, fully filled orbitals are more stable, so one electron from 4s orbital transfers into 3d orbital. Electronic configuration of Neon is-

Ne10 = 1s2, 2s2, 2p6

Therefore, using inert gas, the configuration of Cu can be represented as-

Cu29 - [Ne] 3s2, 3p6, 3d10, 4s1


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688.

Assertion: Cuprous ion (Cu+) is colorless whereas cupric ion (Cu2+) is blue in the aqueous solution.
Reason: Cuprous ion (Cu+) has unpaired electrons while cupric ion (Cu2+) does not.

  • If both assertion and reason are true and reason is a correct explanation of the assertion.

  • If both the assertion and reason are true but the reason is not a correct explanation of the assertion.

  • If the assertion is true but the reason is false.

  • If both the assertion and reason are false.


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689.

The stable bivalency of Pb and trivalencey of Bi is:

  • due to d contraction in Pb and Bi

  • due to relativistic contraction of the 6s orbitals of Pb and Bi, leading to inert pair effect

  • due to screening effect

  • due to the attainment of noble liquid configuration


690.

A magnetic moment of 1.73 BM will be shown by one among the following

  • [Cu(NH3)4]2+

  • [Ni(CN)4]2-

  • TiCl4

  • [CoCl6]4-


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