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 Multiple Choice QuestionsShort Answer Type

61.

Complete the following reaction equation:
straight R subscript 2 SiCl subscript 2 space plus space straight H subscript 2 straight O space rightwards arrow

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 Multiple Choice QuestionsLong Answer Type

62. How do elements of group 13 occur in nature?
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63.

Discuss the characteristics of group 13 elements in terms of:
(i) Atomic and ionic radii
(ii) ionisation enthalpy
(iii) Density, melting point and boiling points.

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 Multiple Choice QuestionsShort Answer Type

64.

How would you explain the lower atomic radius of Ga as compared to Al ?

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 Multiple Choice QuestionsLong Answer Type

65. Discuss the characteristics of group 13 elements in terms of :
(i) Electronegativity        
(ii) Nature of bonds        
(iii) Oxidation states. 
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66.

Explain the following:
(i)  Boron is trivalent
(ii) Boron and aluminium tend to form covalent compounds.

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67.

Discuss the pattern of variation in the oxidation states of B(Boron) to Tl(Thallium).
Or
What is inert pair effect? Illustrate it with reference to Boron family. 

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 Multiple Choice QuestionsShort Answer Type

68.

How can you explain the higher stability of BCl3 as compared to TlCl3?

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69.

Standard electrode potential values straight E to the power of circled dash space for space Al to the power of 3 plus end exponent divided by Al space is space minus 1.66 straight V and that of Tl to the power of 3 plus end exponent divided by Tl is +1.26 V. Predict about the formation of M3+ ion in solution and compare the electropositive character of the two metals. 

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70.

What are electron deficient compounds? Is BCl3 electron deficient species?


Species in which the central atom either does not have eight electrons in the valence shell or those which have 8 electrons in the valence shell but can expand their covalency beyond 4 due to the presence of d-orbitals are called electron deficient molecules.

BCl3 is an electron deficient compound because the central boron atom has only six electrons. As a result, it accepts a pair of electrons from NH3 to form an adduct.

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