In some of the reactions, thallium resembles aluminium whereas i

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 Multiple Choice QuestionsLong Answer Type

91. When metal X is treated with sodium hydroxide, a white precipitate (A) is obtained, which is soluble in excess of NaOH to give soluble complex (B). Compound (A) is soluble in dilute HCl to form compound (C).
The compound (A) when heated strongly gives (D) which is used to extract metal. Identify (X), (A), (B), (C) and (D). Write suitable equations to support their identities. 
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92.

Aluminium trifluoride is insoluble in anhydrous HF but dissolves on the addition of NaF. Aluminium trifluoride precipitates out of the resulting solution when gaseous BF3 is bubbled through. Give reasons. 

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93.

Discuss similarities in properties among the group 13 elements. 

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94.

Boron exhibits anomalous behaviour in the company of other members of group 13. Explain.

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95.

Discuss the diagonal relationship of boron with silicon. 

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 Multiple Choice QuestionsShort Answer Type

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96.

In some of the reactions, thallium resembles aluminium whereas in others it resembles with group 1 metals. Support this statement by giving some evidences. 


Thallium resembles aluminium:

(i) Al shows a uniform oxidation state of + 3 and Tl also shows +3 oxidation states in its certain compounds such as TlCl3, Tl2O3 etc.

(ii) Both Al and Tl form octahedral complexes [AlF6]3– and [TlF6]3– respectively.

Thallium resembles group 1 metals:

(i) Thallium (Tl) and group 1 metals show an oxidation state of + 1. Thallium shows an oxidation state of + 1 due to inert pair effect in some of its compounds like Tl2O, TICl6 TIClO4 etc.

(ii) Like group 1 oxides, Tl2O is strongly basic.

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97.

What are borones(boron hybrides)?

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98.

What is the action of:
(a) H2O (b) LiH on B2H6?

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99.

Write balanced equations for:
straight B subscript 2 straight H subscript 6 space plus space straight H subscript 2 straight O space space rightwards arrow

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100.

Write balanced equations for:

NaH space plus space straight B subscript 2 straight H subscript 6 space space rightwards arrow

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