Which one of the following molecules contains no pi -bond?
CO2
H2O
SO2
SO2
B.
H2O
All the molecules have O atom with lone pairs, but in H2O the H atom has no vacant orbital for pi-bonding. That's why it does not have any pi- bond.
In all other given molecules, the central atom because of the presence of vacant orbitals is capable to farm Pi- bonds.
Which of the following statements is not valid for oxoacids of phosphorus?
Orthophosphoric acid is used in the manufacture of triple superphosphate
All oxoacids contain tetrahedral four coordinated phosphorus
All oxoacids contain tetrahedral four coordinated phosphorus
In Which of the following arrangement, the given sequence is not strictly according to the property indicated against it ?
HF < HCl< HBr < HI : increasing acidic strength
H2O < H2S < H2Se < H2Te : increasing pKa values.
NH3 < PH3 < AsH3 < SbH3 : increasing acidic character
NH3 < PH3 < AsH3 < SbH3 : increasing acidic character
The stability of +1 oxidation state among Al, Ga, In and TI increases in the sequence
Ga<In< Al<Tl
Al<Ga<In<Tl
Tl<In<Ga<Al
Tl<In<Ga<Al
The variation of the boiling point of the hydrogen halides in the order HF > HI > HBr > HCl. What explains the higher boiling point of hydrogen fluoride?
The electronegativity of fluorine is much higher than for other elements in the group
There is strong hydrogen bonding between HF molecules
The bond energy of HF molecules is greater than in other hydrogens halides
The bond energy of HF molecules is greater than in other hydrogens halides
Strong reducing behaviour of H3PO4 is due to
the presence of one -OH group and two P-H bonds
high electron gain enthalpy of phosphorous
the high oxidation state of phosphorus
the high oxidation state of phosphorus
Oxidation states of P in H4P2O5, H4P2O6, H4P2O7, are respectively
+3, +5, +4
+5, +3, +4
+5, +4,+3
+5, +4,+3