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 Multiple Choice QuestionsMultiple Choice Questions

1141.

XeF2 is isostructural with 

  • TeF2

  • ICl-2

  • SbCl3

  • SbCl3

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1142.

Which one of the following molecules contains no pi -bond?

  • CO2

  • H2O

  • SO2

  • SO2

1628 Views

1143.

Which of the following is a polar molecule?

  • BF3

  • SF4

  • SiF4

  • SiF4

1421 Views

1144.

Which of the following statements is not valid for oxoacids of phosphorus? 

  • Orthophosphoric acid is used in the manufacture of triple superphosphate

  • Hypophosphorous acid is a diprotic acid
  • All oxoacids contain tetrahedral four coordinated phosphorus

  • All oxoacids contain tetrahedral four coordinated phosphorus

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1145.

In Which of the following arrangement, the given sequence is not strictly according to the property indicated against it ? 

  • HF < HCl< HBr < HI : increasing acidic strength

  • H2O < H2S < H2Se < H2Te : increasing pKa values.

  • NH3 < PH3 < AsH3 < SbH : increasing acidic character

  • NH3 < PH3 < AsH3 < SbH : increasing acidic character


B.

H2O < H2S < H2Se < H2Te : increasing pKa values.

(a,c) As we move from top to bottom in a group, the acidic strength of hydrides increases. Therefore, order of acidic strength of hydrides of VA and VII A group elements is

NH3 < PH3 < AsH3< SbH3
HF<HCl < HBr <HI

b) As we move from top to bottom in a group acidic nature (Ka) increases. Therefore, pKa decreases. Thus, order of pKa value of hydrides of VI A group  elements is
H2O > H2S >H2Se > H2Te

d) On moving from top to bottom, oxidising power of oxides increases. Thus, order of oxidising power of oxides of IVA group elements is 
CO2 < SiO< SnO2 < PbO2
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1146.

The stability of +1 oxidation state among Al, Ga, In and TI increases in the sequence

  • Ga<In< Al<Tl

  • Al<Ga<In<Tl

  • Tl<In<Ga<Al

  • Tl<In<Ga<Al

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1147.

The variation of the boiling point of the hydrogen halides in the order HF >  HI > HBr > HCl. What explains the higher boiling point of hydrogen fluoride?

  • The electronegativity of fluorine is much higher than for other elements in the group

  • There is strong hydrogen bonding between HF molecules

  • The bond energy of HF molecules is greater than in other hydrogens halides

  • The bond energy of HF molecules is greater than in other hydrogens halides

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1148.

Which of the following oxide is amphoteric?

  • SnO2

  • CaO2

  • SiO2

  • SiO2

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1149.

Strong reducing behaviour of H3PO4 is due to

  • the presence of one -OH group and two P-H bonds

  • high electron gain enthalpy of phosphorous 

  • the high oxidation state of phosphorus

  • the high oxidation state of phosphorus

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1150.

Oxidation states of P in H4P2O5, H4P2O6, H4P2O7, are respectively

  • +3, +5, +4

  • +5, +3, +4

  • +5, +4,+3

  • +5, +4,+3

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