Which of the following statements is not valid for oxoacids of phosphorus?
Orthophosphoric acid is used in the manufacture of triple superphosphate
All oxoacids contain tetrahedral four coordinated phosphorus
All oxoacids contain tetrahedral four coordinated phosphorus
In Which of the following arrangement, the given sequence is not strictly according to the property indicated against it ?
HF < HCl< HBr < HI : increasing acidic strength
H2O < H2S < H2Se < H2Te : increasing pKa values.
NH3 < PH3 < AsH3 < SbH3 : increasing acidic character
NH3 < PH3 < AsH3 < SbH3 : increasing acidic character
The stability of +1 oxidation state among Al, Ga, In and TI increases in the sequence
Ga<In< Al<Tl
Al<Ga<In<Tl
Tl<In<Ga<Al
Tl<In<Ga<Al
The variation of the boiling point of the hydrogen halides in the order HF > HI > HBr > HCl. What explains the higher boiling point of hydrogen fluoride?
The electronegativity of fluorine is much higher than for other elements in the group
There is strong hydrogen bonding between HF molecules
The bond energy of HF molecules is greater than in other hydrogens halides
The bond energy of HF molecules is greater than in other hydrogens halides
Which of the following oxide is amphoteric?
SnO2
CaO2
SiO2
SiO2
A.
SnO2
SnO2 is an amphoteric oxide because it reacts with acids as well as bases to form corresponding salts.
SnO2 +4HCl → SnCl4 +2H2O
SnO2 + 2 NaOH → Na2SnO3 + H2O
Strong reducing behaviour of H3PO4 is due to
the presence of one -OH group and two P-H bonds
high electron gain enthalpy of phosphorous
the high oxidation state of phosphorus
the high oxidation state of phosphorus
Oxidation states of P in H4P2O5, H4P2O6, H4P2O7, are respectively
+3, +5, +4
+5, +3, +4
+5, +4,+3
+5, +4,+3