Account for the following:(i) Lithium can not form monovalent

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121.

Discuss the extraction of lithium.

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What difficulties arise in the extraction of lithium?

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What happens when:
(i) Lithium reacts with air
(ii) Lithium reacts with water
(iii) Lithium reacts with halogen
(iv) Lithium reacts with acids?

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124.

Account for the following:
(i) Lithium can not form monovalent cation (Li+) easily.
(ii) Lithium iodide is more covalent than lithium fluoride.


(i) The ionisation enthalpy of lithium is maximum in the group. Therefore, it can not form monovalent cation (Li+) so easily as compared to the other alkali metals.

(ii) According to Fajan rule, Li+ ion can polarise I ion more than the ion because of the bigger size of the anion. Therefore, lithium iodide has more covalent character than lithium fluoride.


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125.

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127.

What difficulities arise in the extraction of sodium? How these difficulties are overcome?

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130.

What happens when:
(i) sodium reacts with hydrogen halide,
(ii) sodium reacts with acetylene,
(iii) sodium is heated with hydrogen and
(iv) sodium is treated with mercury ?

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