Important Questions of Thermodynamics Chemistry | Zigya

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 Multiple Choice QuestionsShort Answer Type

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231.

What are important consequences of lattice enthalpies?

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 Multiple Choice QuestionsLong Answer Type

232. What is Born-Haber cycle? How can we obtain lattice enthalpy of a solid with its help? 
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233.

How can the lattice enthalpy of an ionic NaCl be determined by using Born-Haber cycle?

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234.

Calculate the lattice enthalpy of KCl crystal from the following data:

Sublimation enthalpy of pottasium (K) = +89 kJ mol-1
Dissociation enthalpy of 1 half Cl subscript 2 left parenthesis straight g right parenthesis
                                          = +122 kJ mol-1
Ionisation enthalpy of K(g) +425 kJ mol-1
Electron gain enthalpy of Cl(g) = -355 kJ mol-1
Enthalpy of formation of KCl left parenthesis increment subscript straight r straight H degree right parenthesis space equals space minus 438 space kJ space mol to the power of negative 1 end exponent



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235.

Calculate the lattice enthalpy of LiF, given that the enthalpy of
(i) sublimation of lithium is 155.2 kJ mol–1
(ii) dissociation of 1/2 mol of F2is 75.3 kJ
(iii) ionization of lithium is 520 kJ mol–1
(iv) electron gain of 1 mol of F(g) is –333 kJ
(v) ∆f H0 ∆fH0 overall is –795 kJ mol–1

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 Multiple Choice QuestionsShort Answer Type

236.

Calculate the lattice enthalpy of MgBr2 from the given data. The enthalpy of formation of MgBr2 according to the reaction

Mg left parenthesis straight s right parenthesis space plus space Br subscript 2 left parenthesis straight l right parenthesis space space space rightwards arrow space space MgBr subscript 2 left parenthesis straight s right parenthesis semicolon space increment subscript straight f straight H to the power of 0 space equals space minus 524 space kJ space mol to the power of negative 1 end exponent
CH subscript 1 superscript 0 space for space Mg left parenthesis straight s right parenthesis space space rightwards arrow space space Mg to the power of 2 plus end exponent left parenthesis straight g right parenthesis space plus space 2 straight e to the power of minus space equals space plus 2187 space kJ space mol to the power of negative 1 end exponent
increment straight H subscript 3 superscript 0 space for space Br subscript 2 left parenthesis straight l right parenthesis space space rightwards arrow space space space space Br subscript 2 left parenthesis straight g right parenthesis space equals space 31 space kJ space mol to the power of negative 1 end exponent
increment straight H subscript 4 superscript 0 space for space Br subscript 2 left parenthesis straight g right parenthesis space equals space 2 space Br left parenthesis straight g right parenthesis space equals space 193 space kJ space mol to the power of negative 1 end exponent
increment straight H subscript 5 superscript 0 space for space Br left parenthesis straight g right parenthesis space plus space straight e to the power of minus left parenthesis straight g right parenthesis space space rightwards arrow space space Br to the power of minus space equals space minus 331 space kJ space mol to the power of negative 1 end exponent
increment straight H subscript 6 superscript 0 space for space Mg to the power of 2 plus end exponent left parenthesis straight g right parenthesis space plus 2 Br to the power of minus left parenthesis straight g right parenthesis space space rightwards arrow space space space MgBr subscript 2 left parenthesis straight s right parenthesis space equals space ?

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 Multiple Choice QuestionsLong Answer Type

237. What do you understand by spontaneous and non-spontaneous processes? 
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238. Is ∆H the only criterion for the feasibility of a process ? Comment.
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239.

The tendency of a system to acquire a state of maximum randomness is the sole criterion for the spontaneity of a process. Comment.

 
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240. “Driving force is the overall tendency of a process to occur.” Comment on, the statement.
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