What are the types of systems? from Chemistry Thermodynamics

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 Multiple Choice QuestionsShort Answer Type

131.

For which molecule bond energy equal to bond dissociation energy?

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132.

What will be the sign of G for the melting of ice at 267K and at 276K?

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133.

How can a non-spontaneous reaction be made spontaneous?

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134.

What will be the value of free energy change when the reaction is in equilibrium?

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135.

What are the types of systems?


Types of systems. The exchange of energy between the system and its surroundings usually takes place in the form of heat or work or both. Based upon this, the systems have been classified into three types:
(i) Open system (ii) Closed system (iii) Isolated system.

(i) Open system: A system is said to be an open system if it exchanges the matter (mass) as well as the energy with its surroundings. All chemical reactions carried in open containers constitute the open system. For example,
(a) Combustion of carbon in an open tube.

(b) Tea placed in a cup.

(ii) Closed system: A system is said to be a closed system if the only exchange of energy is possible between system and surroundings and exchange of matter (mass) is not possible. All chemical reactions carried in closed containers constitute closed system e.g.

(a) Decomposition of calcium carbonate in a closed tube.

(b) Tea placed in a tea-pot.

(iii) Isolated system: A system which can neither exchange energy nor matter (mass) with its surroundings is called an isolated system. All chemical reactions carried in a closed container insulated from all sides represent the isolated system. For example.

(a) Neutralisation reaction between NaOH and HCl carried in a thermos flask.



(b) Tea placed in a thermos flask.

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136. Define: (i) State variables (ii) State functions.
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137.

What are homogeneous and heterogeneous systems?

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 Multiple Choice QuestionsLong Answer Type

138.

What do you understand by:
(i) Isothermal process
(ii) Adiabatic process
(iii) Isobaric process
(iv) Isochoric process
(v) Cyclic process?

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139.

Give the points of difference between reversible process and irreversible process.

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 Multiple Choice QuestionsShort Answer Type

140.

Classify the following processes as reversible or irreversible:
(i) mixing of two gases by diffusion.
(ii) dissolution of sodium chloride in water
(iii) evaporation of water at 373 K at 1 atm pressure
(iv) expansion of a gas in vacuum.

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