The heat of neutralization of a strong base and a strong aci

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 Multiple Choice QuestionsMultiple Choice Questions

671.

An endothermic reaction with high activation energy for the forward reaction is given by the diagram


672.

For the reaction of one mole of zinc dust with one mole of sulphuric acid in a bomb calorimeter, U and w corresponds to

  • U < 0, w = 0

  • U < 0, w < 0

  • U > 0, w = 0

  • U > 0, w > 0


673.

Assertion : Water in liquid state is more stable than ice at room temperature.

Reason : Water in liquid form has higher entropy than ice.

  • If both assertion and reason are true and reason is the correct explanation of the assertion.

  • If both assertion and reason are true but reason is not the correct explanation of the assertion.

  • If assertion is true, but reason is false.

  • Both assertion and reason are false statements.


674.

Assertion : First ionization energy for nitrogen is lower than oxygen.

Reason : Across a period effective nuclear charge decreases.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


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675.

The heat of neutralization of a strong base and a strong acid is 57 kJ. The heat released when 0.5 mole of HNO3 solution is added to 0.20 moles of NaOH solution, is :

  • 11.4 kJ

  • 34.7 kJ

  • 23.5 kJ

  • 58.8 kJ


A.

11.4 kJ

Heat of neutralization (H)= 57 kJ, mole of HNO3 = 0.5 mole and mole of NaOH = 0.2 mole. When HNO3 solution is added to NaOH solution, then 0.2 mole of HNO3 solution will combine with 0.2 mole of OH- ions of NaOH solution.

 Heat released= H x 0.2 = 57 x 0.2 = 11.4 kJ.


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676.

How much energy is released when 6 moles of octane is burnt in air? Given Hf° for CO2(g) , H2O(g) and C8H18(l)  respectively are - 490, -240 and +160 kJ/mol.

  • -6.2 kJ

  • -37.4 kJ

  • -35.5 kJ

  • -20.0 kJ


677.

For the equilibrium H2O(l)  H2O(g) at 1 atm and 298K.

  • standard free energy change is equal to zero (G°= 0)

  • free energy change is less than zero (G° < 0)

  • standard free energy change is less than zero (G°< 0)

  • standard free energy change is greater than zero (G° > 0).


678.

Of the following which change will shift the reaction towards the product?

I2(g) 2I(g), Hf° (298K) = +150kJ

  • Increase in concentration of I

  • Decrease in concentration of I2

  • Increase in temperature

  • Increase in total pressure


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679.

One gram sample of NH4NO3 is decomposed in a bomb calorimeter. The temperature of the calorimeter increases by 6.12 K. The heat capacity of the system is 1.23 kJ/g/deg. What is the molar heat of decomposition for NH4NO3 ?

  • -7.53 kJ/mol

  • -398.1 kJ/mol

  • -16.1 kJ/mol

  • -602 kJ/mol


680.

Which one of the following has S° greater than zero?

  • CaO(s) + CO2(g)  CaCO3(s)

  • NaCl(aq) NaCl(s)

  • NaNO3(s)  Na+(aq) + NO3-(aq)

  • N2(g) + 3H2(g)  2NH3(g)


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