The compound A on treatment with Na gives B, and with PCl5 gives

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 Multiple Choice QuestionsMultiple Choice Questions

311.

Which one is the most acidic compound?

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312.

Which one is the correct order of acidity?

  • CH2= CH2> CH3– CH = CH2> CH3– C ≡ CH > CH ≡ CH

  • CH ≡  CH > CH3– C ≡  CH > CH2= CH2> CH3– CH3

  • CH ≡ CH > CH2= CH2> CH3– C ≡  CH >CH3– CH3

  • CH ≡ CH > CH2= CH2> CH3– C ≡  CH >CH3– CH3

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313.

Identify A and predict the type of reaction

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314.

The heating of phenyl-methyl ethers with HI produces.

  • Ethyl chlorides

  • Iodobenzene

  • Phenol

  • Phenol

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315.

The compound A on treatment with Na gives B, and with PCl5 gives C. B and C react together to give diethyl ether. A, B and C are in the order

  • C2H5OH, C2H6, C2H5Cl

  • C2H5OH, C2H5Cl, C2H5ONa

  • C2H5OH, C2H5ONa, C2H5Cl

  • C2H5Cl, C2H6, C2H5OH


C.

C2H5OH, C2H5ONa, C2H5Cl


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316.

In the reaction,

The electrophile involved is

  • Dichloromethyl cation (C+HCl2)

  • Formyl cation (C+HO)

  • Dichlorocarbene (:CCl2)

  • Dichloromethyl anion (C-HCl2)


317.

The product (P) is


318.

Aqueous 10% NaHCO3 solution is used as a reagent for identifying 'A'. Which of the following compounds yield 'A' on hydrolysis?

  • CH3COOC2H5

  • C2H5-COO-C2H5

  • CH3CHO

  • CH3CH2OH


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319.

When a mixture of 1-hexanol and hexanoic acid in diethyl ether is shaken with an aqueous NaHCO3 solution, then which of the following is right distribution?

  • In ether  In sodium bicarbonate solution
    Sodium hexanoate 1- hexanol
  • 1- hexanol Hexanoic acid
  • 1- hexanol Sodium hexanoate
  • Hexanoic acid 1- hexanol

320.

The correct order of increasing acidic strength is

  • phenol < ethanol < chloroacetic acid < acetic acid

  • ethanol < phenol < chloroacetic acid < acetic acid

  • ethanol < phenol < acetic acid < chloroacetic acid

  • chloroacetic acid < acetic acid < phenol < ethanol


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