Which one is the correct order of acidity?
CH2= CH2> CH3– CH = CH2> CH3– C ≡ CH > CH ≡ CH
CH ≡ CH > CH3– C ≡ CH > CH2= CH2> CH3– CH3
CH ≡ CH > CH2= CH2> CH3– C ≡ CH >CH3– CH3
CH ≡ CH > CH2= CH2> CH3– C ≡ CH >CH3– CH3
The heating of phenyl-methyl ethers with HI produces.
Ethyl chlorides
Iodobenzene
Phenol
Phenol
The compound A on treatment with Na gives B, and with PCl5 gives C. B and C react together to give diethyl ether. A, B and C are in the order
C2H5OH, C2H6, C2H5Cl
C2H5OH, C2H5Cl, C2H5ONa
C2H5OH, C2H5ONa, C2H5Cl
C2H5Cl, C2H6, C2H5OH
In the reaction,
The electrophile involved is
Dichloromethyl cation (C+HCl2)
Formyl cation (C+HO)
Dichlorocarbene (:CCl2)
Dichloromethyl anion (C-HCl2)
Aqueous 10% NaHCO3 solution is used as a reagent for identifying 'A'. Which of the following compounds yield 'A' on hydrolysis?
CH3COOC2H5
C2H5-COO-C2H5
CH3CHO
CH3CH2OH
A.
CH3COOC2H5
NaHCO3 is basic in nature so it is used in the identification of acid only. In the given compound only ester (CH3COOC2H5) on hydrolysis gives acid as
When a mixture of 1-hexanol and hexanoic acid in diethyl ether is shaken with an aqueous NaHCO3 solution, then which of the following is right distribution?
In ether | In sodium bicarbonate solution |
Sodium hexanoate | 1- hexanol |
1- hexanol | Hexanoic acid |
1- hexanol | Sodium hexanoate |
Hexanoic acid | 1- hexanol |
The correct order of increasing acidic strength is
phenol < ethanol < chloroacetic acid < acetic acid
ethanol < phenol < chloroacetic acid < acetic acid
ethanol < phenol < acetic acid < chloroacetic acid
chloroacetic acid < acetic acid < phenol < ethanol