The reaction ,2CH3-CO-OC2H5 →C2H5ONa CH3-CO-CH2-CO

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 Multiple Choice QuestionsMultiple Choice Questions

581.

What is the correct IUPAC name of :

  • 4 - methoxy - 2 - nitrobenzaldehyde

  • 4 - formyl - 3 - nitro anisole

  • 4 - methoxy - 6 - nitrobenzaldehyde

  • 2 - formyl - 5 - methoxy nitrobenzene


582.

The reaction ,

CH3-CO-OCH3 + C2H5OH H+ or OH- CH3-CO-OC2H5 + CH3OH is called :

  • Perkin's reaction

  • Claisen Schmidt reaction

  • Esterification

  • Trans-esterification


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583.

The reaction ,

2CH3-CO-OC2H5 C2H5ONa CH3-CO-CH2-CO-OC2H5 + C2H5OH is called :

  • Etard reaction

  • Perkin's reaction

  • Claisen condensation

  • Claisen Schmidt reaction


C.

Claisen condensation

2 molecules of ester condense to give β- keto ester ,in presence of alkali .This reaction is called Claisen condensation .

2CH3-CO-OC2H5 C2H5ONa CH3-CO-CH2-CO-OC2H5ethyl aceto acetate + C2H5OH


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584.

Formaldehyde reacts with ammonia to give urotropine .The formula of urotropine is :

  • (CH2)6N4

  • (CH2)4N3

  • (CH2)6N6

  • (CH2)3N3


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585.

CH6CO5NHCH3 can be converted into C6H5CH2NHCH3 by

  • NaBH4

  • H2-Pd/C

  • LiAl4

  • Zn-Hg/HCl


586.

The cyanohydrin of which compound, gives lactic acid on hydrolysis ?

  • HCHO

  • CH3CHO

  • C6H5CHO

  • CH3COCH3


587.

The intermediate formed in aldol condensation is :

  • aldol

  • carbanion

  • alcohol

  • alpha-hydrogen ester


588.

The compound most suitable for the preparation of cyanohydrin is :

  • C2H5COOH

  • C6H5NH2

  • C2H5COC2H5

  • C2H5-C2H5


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589.

CH3COCH3 car be converted to CH3CH2CH3 by the action of :

  • HIO3

  • HNO3

  • HI

  • H3PO3


590.

Which of the following has the highest dipole moment ?

  • (H)2-C=O

  • (CH3)2-C=C-(H)2

  • CH3-CH=CH-CH3

  • CH3-C(Cl)=C(Cl)-CH3


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