The compound which on reaction with aqueous HNO2 at low temperature produces an oily nitrosoamine is
methyl amine
ethyl amine
diethyl amine
aniline
Amongst the following the most basic compund is
benzyl amine
aniline
acetanilide
p -nitroaniline
Acetylene reacting with HCN in presence of Ba(CN)2 gives
vinyl cyanide
1,1-dicyanoethane
1,2-dicyanoethane
None of the above
In dehydrolysing reaction, CH3CONH2 CH3CN + H2O the hybridisation state of carbon is changed from
sp3 to sp2
sp to sp2
sp2 to sp
sp to sp3
RCONH2 + Br2 + KOH → Amine
This reaction is
Carbyl amine reaction
Mustard oil reaction
Hofmann bromamde reaction
Cannizaro reaction
Mark the correct statement.
Methylamine is slightly acidic
Methylamine is less basic than NH3
Methylamine is stronger base than NH3
Methylamine forms salt with alkalies
C.
Methylamine is stronger base than NH3
Basicity depends upon the availability of lone pair of electrons for donation. Presence of electron releasing substituent (like -CH3, -C2H5) increases the electron density over nitrogen, thus makes nitrogen more capable for donating electrons. Hence, methylamine (CH3H2)is a stronger base than NH3.
Due to its basic nature, CH3NH2 forms salt with acids.
In the carbylamine reaction, R-X is converted to R-Y via the intermediate Z. R-X, R-Y and Z, respectively, are
RNH2, RNC, Carbene
RNH2, RNC, nitrene
RNC, RNH2, carbene
ROH, RNC, nitrene