Which of the following compounds will give red colour on Lassaigne test?
NaCNS
NH2CSNH2 (thiourea)
p-NH2C6H4SO3H (p- aminobenzene sulphonic acid)
all of the above
D.
all of the above
When nitrogen and sulphur both are present in the organic compound, they combine during fusion to form sodium thiocyanate (sulphocyanide). This when heated with FeSO4 or FeCl3, produces a red blood colouration due to ferric thiocyanate (or sulphocyanide). Thus, thiourea and p-aminobenzene sulphonic acid give red colour on lassaigne test.
A positive carbylamine test is given by
I. N, N-dimethylaniline
II. 2, 4-dimethylamine
III. N-methyl-o-methylaniline
IV. p-methylbenzyl amine
(II) and (IV)
(I) and (IV)
(II) and (III)
(I) and (II)
The IUPAC name of the following compound is
2-carbamoylhexanal
2-carbamoylhex-3-enal
2-methyl-6-oxohex-3-enamide
6-keto-2-methyl hexamide
Cyclohexylamine and aniline can be distinguished by
Hinsberg test
Carbylamine test
Lassaigne test
Azo dye test