Nitration of phenyl benzoate yields the product from Chemistry A

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 Multiple Choice QuestionsMultiple Choice Questions

181.

Which of the following compounds will give red colour on Lassaigne test?

  • NaCNS

  • NH2CSNH2 (thiourea)

  • p-NH2C6H4SO3H (p- aminobenzene sulphonic acid)

  • all of the above


182.

A positive carbylamine test is given by

I. N, N-dimethylaniline

II. 2, 4-dimethylamine

III. N-methyl-o-methylaniline

IV. p-methylbenzyl amine

  • (II) and (IV)

  • (I) and (IV)

  • (II) and (III)

  • (I) and (II)


183.

Wat will be the final product of following reaction sequence?


184.

The IUPAC name of the following compound is

 

  • 2-carbamoylhexanal

  • 2-carbamoylhex-3-enal

  • 2-methyl-6-oxohex-3-enamide

  • 6-keto-2-methyl hexamide


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185.

Which one of the following is the correct structure of sulphapyridine?


186.

Iidentify Z in the following reaction:


187.

H3CCONH2 + Br2 + 4 NaOH  Y + Na2CO3+ 2NaBr + 2H2O

  • H3CCH2NH2

  • H3CNH2

  • H3CCOBr

  • HCONH2


188.

Which is the strongest base among the following?

  • H3CNH2


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189.

Cyclohexylamine and aniline can be distinguished by

  • Hinsberg test

  • Carbylamine test

  • Lassaigne test

  • Azo dye test


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190.

Nitration of phenyl benzoate yields the product


C.

It is an electrophilic aromatic substitution reaction. Because the COO- acts as an electron wthdrawing group to one phenyl group and a moderate electron donating group to the other phenyl group the nitration wll occur on the phenyl group where COO- is acting as an
electron donating group.

The major product of the nitration will have the -NO2 in the para position because the ortho positions partially blocked by the large COPh group.


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