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 Multiple Choice QuestionsMultiple Choice Questions

291.

The reaction

is called

  • Claisen-Schmidt reaction

  • Kolbe-Schmidt reaction

  • Schmidt reaction

  • Kolbe's reaction


292.

Which of the following amines, can give N-nitrosoamine on treatment with HNO2?


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293.

Assertion: Anilinium chloride is more acidic than ammonium chloride.

Reason : Anilinium chloride is resonance stabilised.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


C.

If assertion is true but reason is false.

Aniline is weaker base than ammonium chloride. In NH4Cl or aliphatic amines, nonbonding electron pair of N is localised and is fully available for coordination with a proton.

C6H5NH3+(strong acid)  C6H5NH2 + H+(weak- conjugate base)

On the other hand, in aniline and other aromatic amines, the non -bonding electron pair delocalised into benzene ring by resonance.

But anilinium ion is less resonance stabilised than aniline.

 


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294.

Which of the following statement is true?

  • Trimethyl amines form a soluble compound with Hinsberg reagent and KOH.

  • Dimethylamines react with KOH and phenol to form an azo dye.

  • Methylamine reacts with nitrous acid and liberates N2 from aq. soln.

  • None of these


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295.

Aniline with CHCl3 and KOH on heating gives :

  • isocyanide

  • cyanide

  • phenol

  • salicylic acid


296.

Correct order of basic nature is :

  • NH3 > CH3NH2 > C6H5NH2

  • C6H5NH> NH3 > CH3NH2

  • CH3NH> NH3 > C6H5NH2

  • none of the above


297.

When acetamide reacts with Br2 and caustic soda , then we get :

  • acetic acid

  • bromoacetic acid

  • methyl amine

  • ethyl amine


298.

The following sequence of reactions on A gives


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299.

Nitrobenzene on treatment with zinc dust and aqueous ammonium chloride gives

  • C6H5N =N-C6H5

  • C6H5NH2

  • C6H5NO

  • C6H5NHOH.


300.

Among the following which one does not act as an intermediate in Hofmann rearrangement?

  • RNCO

  • RCON..

  • RCON..HBr

  • RNC


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