In which of the following molecules the central atom does not have sp3 hybridisation?
CH4
SF4
BF4-
BF4-
From the following bond energies:
H-H bond energy: 431.37 kJ mol-
C=C bond energy: 606.10 kJ mol-
C- C bond energy: 336.49 kJ mol-
C-H bond energy: 410.50 kJ mol-
Enthalpy for the reaction,
will be
1523.6 kJ mol-
-243.6 kJ mol-
-1200. kJ mol-
-1200. kJ mol-
According to MO theory which of the following lists ranks the nitrogen species in terms of increasing bond order?
The state of hybridization of C2, C3, C5 and C6 of the hydrocarbon,
is in the following sequence
sp, sp3, sp2 and sp3
sp3, sp2, sp2 and sp
sp,sp2,sp2 and sp3
sp,sp2,sp2 and sp3
In which of the following molecules/ions BF3, NO2-, NH2- and H2O, the central atom is sp2 hybridised?
NO2- and NH2-
NH2- and H2O
NO2- and H2O
NO2- and H2O
D.
NO2- and H2O
For sp2 hybridization, there must be either 3 sigma bonds or two sigma bonds and one lone pair of electrons in the molecules or ions.
In BF3 molecule, a number of sigma bond is 3 ie, sp2 hybridization.
In NO2- molecule, the number of sigma bond is 2 and the number of lone pairs is 2 ie, sp3 hybridization.
In NH2-molecule, the number of sigma bond is 2 and the number of lone pairs is 2 ie, sp3 hybridization.
In H2O molecule, the number of sigma bond is 2 and number of the lone pair are 2 ie, sp3 hybridization.
Thus, in BF3 and NO2- central atom is sp2 hybridised.
The angular shape of ozone molecule (O3) consists of
1 sigma and 2 pi bonds
2 sigma and 2 pi bonds
1 sigma and 1 pi bonds
1 sigma and 1 pi bonds
Four diatomic solutions of the following were prepared in water separately. Which one of the solutions will record the highest pH?
Bond dissociation enthalpy of H2, Cl2 and HCl and 434, 242 and 431 kJ mol-1 respectively. Enthalpy of formation of HCl is
93 kJ mol-1
-245 kJ mol-1
-39 kJ mol-1
-39 kJ mol-1
In the hydrocarbon
The state of hybridization of carbon 1, 3, and 5 are in the following sequence
sp2, sp, sp3
sp, sp3, sp2
sp, sp2, sp3
sp, sp2, sp3