Which one of the following order is correct for the first ionisat

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 Multiple Choice QuestionsMultiple Choice Questions

31.

An f-shell containing 6 unpaired electrons can exchange

  • 6 electrons

  • 9 electrons

  • 12 electrons

  • 15 electrons


32.

Among the elements Ca, Mg, P and Cl, the order of increasing atomic radii is

  • Mg< Ca< Cl< P

  • Cl <P <Mg< Ca

  • P <Cl< Ca< Mg

  • Ca <Mg <P < Cl


33.

Among the following which one has the highest cation of anion size ratio?

  • Csl

  • CsF

  • LiF

  • NaF


34.

What is the value of electron gain enthalpy of Na if IE1 of Na = 5.1 eV?

  • -5.1 eV

  • -10.2 eV

  • +2.55 eV

  • +10.2eV


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35.

Assertion (A): K, Rb and Cs form superoxides.

Reason (R): The stability of the superoxides increases from 'K' to 'Cs' due to decrease in lattice energy.

The correct answer is

  • Both (A) and (R) are true and (R) is the correct explanation of (A).

  • Both (A) and (R) are true but (R) is not the correct explanation of (A)

  • (A) is true but (R) is not true

  • (A) is not true but (R) is true


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36.

Which one of the following order is correct for the first ionisation energies of the elements?

  • B <Be <N < O

  • Be <B <N < O

  • B <Be <O <N

  • B <O <Be <N


C.

B <Be <O <N

D.

B <O <Be <N

First ionisation energy increases in a period. Thus, the first IE of the elements of the second period should be as follows
                       Be <B <N <O
But in practice, the elements do not follow the above order. The first IE of these elements is
                       B <Be <O < N

The lower IE of B than that of Be is because in B (1s2, 2s2,2p1), electron is to be removed from 2p which is easy while in Be (1s2, 2s2), electron is to be removed from 2s which is difficult. The low IE of O than that of N is because of the half-filled 2p orbitals in N (1s2, 2s2,2p3).


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37.

The oxidation number of oxygen in KO3, Na2O2 is

  • 3, 2

  • 1, 0

  • 0, 1

  • -0.33, -1


38.

What is the fuel of atomic pile ?

  • Thorium

  • Sodium

  • Uranium

  • Petroleum


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39.

The maximum number of unpaired electrons is present in

  • Fe

  • Cu

  • Co

  • Ni


40.

The pair, that is referred as 'chemical twins' is

  • Ac, Cf

  • Hf, Ta

  • Tc, Re

  • La, Ac


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