The sequence of ionic mobility in aqueous solution is  from Ch

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 Multiple Choice QuestionsMultiple Choice Questions

221.

Among the following which one has the highest cation to anion size ratio?

  • CsI

  • CsF

  • LiF

  • LiF

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222.

Which one of the element with the following outer orbital configuration may exhibit the largest number of oxidation states?

  • 3d5,4s2

  • 3d5,4s1

  • 3d5,4s2

  • 3d5,4s2

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223.

Oxidation number of P in PO43-, of S in SO42- and that of Cr in Cr2O72- are respectively,

  • +5,+6 and +6

  • +3, + 6 and +5

  • +5,+3 and +6

  • +5,+3 and +6

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224.

Amongst the elements with following electronic configuration, which one of them may have the highest ionisation energy?

  • [Ne] 3s2 3p3

  • [Ne] 3s2 3p2

  • [Ar] 3d10, 4s2 4p3

  • [Ar] 3d10, 4s2 4p3

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225.

The correct order of decreasing second ionisation enthalpy of Ti (22), V (23), Cr(24) and Mn (25) is 

  • Cr > Mn> V > Ti

  • V > Mn > Cr >Ti

  • Mn > Cr> Ti >V

  • Mn > Cr> Ti >V

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226.

The sequence of ionic mobility in aqueous solution is 

  • K+ > Na+ > Rb+ > Cs+

  • Cs+ > Rb+ > K+ >Na+

  • Rb+ > K+> Cs+ > Na+

  • Rb+ > K+> Cs+ > Na+


B.

Cs+ > Rb+ > K+ >Na+

The smaller the size of ion, the greater the degree of hydration.



Generally in a group size or radii of ions increases, So Li has the smallest size thus bind a maximum number of water molecules with itself and becomes largest in size (in aqueous solution). Hence, the order of ionic radii (size) of alkali metal ions in aqueous solution is 

Li+ > Na+ > K+> Rb+ >Cs+

Thus, the order of mobility 


Li+ > Na+ > K+> Rb+ >Cs+
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227.

Which of the following oxidation states are the most characteristics for lead and tin respectively? 

  • +4,+2

  • +2,+4

  • +4,+4

  • +4,+4


228.

Consider the following sets of quantum numbers:


  n l m s
i) 3 0 0 +1/2
ii) 2 2 1 +1/2
iii) 4 3 -2 -1/2
iv) 1 0 -1 -1/2
v) 3 2 3 +1/2

Which of the following sets of quantum number is not possible? 
  • ii, iii and iv

  • i, ii, iii and iv

  • ii, iv and v

  • ii, iv and v


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229.

With which of the following electronic configuration an atom has the lowest ionisation enthalpy? 

  • 1s2 2s22p5

  • 1s2 2s22p3

  • 1s2 2s22p5 3s1

  • 1s2 2s22p5 3s1


230.

Identify the correct order of the size of the following:

  • Ca2+ < K+<Ar < S2- < Cl-

  • Ca2+ < K+ < Ar < Cl-< S2-

  • Ar < Ca2+ <K+ <Cl- <S2-

  • Ar < Ca2+ <K+ <Cl- <S2-


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