The decreasing nucleophilicity of the following is:
I. CH3S- II. CH3O-
III. -OH IV. EtO-
II > III > 1V > I
III > IV > I > II
IV > III > I > II
II < I < IV < III
C.
IV > III > I > II
Acidity is explained as
CH3SH > CH3OH > H2O > EtOH
Basicity : CH3S- < CH3O- < -OH < EtO-
When nucleophilic centre is different (CH3S- and CH3O-) and they are from the same group, nucleophilicity is opposite to basicity.
Nucleophilicity EtO- > -OH > CH3S- > CH3O-
Hence, the answer is (c)
When H2S gas is passed in a metal sulphate solution in presence of NH4OH, a white precipitate is produced. The metal is identified as
Zn
Fe
Pb
Hg
Which of the following electronic configuration represents noble gas?
ns2np6
ns2np5
ns2np4
ns2np3
The correct order of ionisation energy of C, N, O, F is :
F < 0 < N < C
F < N < C < 0
C < N < 0 < F
C < 0 < N < F
For the process ,
X (g) + e- X- (g) ; H = x
and X- (g) X (g) + e- ; H = y
select correct alternate
Ionisation energy of x- (g) is y
Electron affinity of X (g) is x
Electron affinity of X (g) is - y
All of the above
Which of the following reactions does not take place?
BF3 + F- B ...(I)
BF3 + 3F- B ...(II)
AlF3 + 3F- Al ...(III)
Only (I)
Only (II)
Only (III)
Only (I) and (III)