Which of the following reactions does not take place?BF3 + F-&nbs

Previous Year Papers

Download Solved Question Papers Free for Offline Practice and view Solutions Online.

Test Series

Take Zigya Full and Sectional Test Series. Time it out for real assessment and get your results instantly.

Test Yourself

Practice and master your preparation for a specific topic or chapter. Check you scores at the end of the test.
Advertisement

 Multiple Choice QuestionsMultiple Choice Questions

261.

Yellow phosphorus is kept in

  • water

  • kerosene

  • ether

  • alcohol


262.

The decreasing nucleophilicity of the following is:

I. CH3S-              II. CH3O-

III. -OH               IV. EtO-

  • II > III > 1V > I

  • III > IV > I > II

  • IV > III > I > II

  • II < I < IV < III


263.

Which will have maximum ionization energy?

  • Na

  • Mg

  • K

  • Bi


264.

Lowest MP and BP is of

  • Ar

  • Xe

  • He

  • Ne


Advertisement
265.

When H2S gas is passed in a metal sulphate solution in presence of NH4OH, a white precipitate is produced. The metal is identified as

  • Zn

  • Fe

  • Pb

  • Hg


266.

Which of the following electronic configuration represents noble gas?

  • ns2np6

  • ns2np5

  • ns2np4

  • ns2np3


267.

The correct order of ionisation energy of C, N, O, F is :

  • F < 0 < N < C

  • F < N < C < 0

  • C < N < 0 < F

  • C < 0 < N < F


268.

Best reagent for the conversion of AgNO3 to Ag is

  • HClO4

  • H3PO2

  • HIO4

  • I2


Advertisement
269.

For the process ,

X (g) + e-  X- (g) ; ΔH = x

and X- (g)  X (g) + e-ΔH = y

select correct alternate

  • Ionisation energy of x- (g) is y

  • Electron affinity of X (g) is x

  • Electron affinity of X (g) is - y

  • All of the above


Advertisement

270.

Which of the following reactions does not take place?

BF3 + F- BF4-          ...(I)

BF3 + 3F- BF63-       ...(II)

AlF3 + 3F-  AlF63-    ...(III)

  • Only (I)

  • Only (II)

  • Only (III)

  • Only (I) and (III)


B.

Only (II)

BF3 forms complex halides of the type [BF4-] in which B atom has C.N. 4, it cannot extend its C.N. beyond 4 due to the non-availability of d-orbitals in its configuration. Hence, BF63- ion (sp3d2 hybridisation) is not formed. On the other hand, Al can extend its C.N. beyond 4 due to the availability of d-orbitals in its configuration.


Advertisement
Advertisement