The strongest base among the following is
C6H5NH2
(C6H5)2NH
NH3
(C2H5)2NH
D.
(C2H5)2NH
(C2H5)2NH is a secondary amine and is strongest base. Basic nature of amines due to presence of lone pair of electron on nitrogen atom which is available for the bond formation with Lewis acid. Due to the +I effect, it is a better amine.
.Initially concentration of A is equal to that of B. The equilibrium concentrations of A and C are equal. Kc is
0.08
0.8
8
80
Match List-I with List-II Choose the correct matching codes from the choices given.
List - I (Hydride) | List - II (Type of hydride) |
A. BeH2 | 1. Complex |
B. AsH3 | 2. Lewis acid |
C. B2H6 | 3. Interstitial |
D. LaH3 | 4. Covalent |
E. LiAlH4 |
5. Intermediate 6. Ionic |
A - 6; B - 2; C - 4; D - 5; E - 1
A - 5; B - 4; C - 2; D - 3; E - 1
A - 6; B - 4; C - 2; D - 3; E - 5
A - 6; B - 4; C - 2; D - 3; E - 1
Two moles of PCl5, is heated in a closed vessel of 2 L capacity. When the equilibrium is attained 40% of it has been found to be dissociated. What is the Kc in mol/dm3?
0.532
0.266
0.133
0.174
The equilibrium constant for the reaction
2NO2 (g) 2NO (g) + O2 (g) is 2 × 10-6 at 185°C. Then the equilibrium constant for the reaction,
4NO (g) + 2O2 (g) 2NO2 (g) at the same temperature would be
2.5 × 10-5
4 × 10-12
2.5 × 1011
2 × 106
The dissociation constant of acetic acid Ka is 1.74 × 10-5 at 298 K. The pH of a solution of 0.1 M acetic acid is :
2.88
3.6
4.0
1.0
0.365g of HCl gas was passed through 100 cm3 of 0.2 M NaOH solution. The pH of the resulting solution would be :
13
9
8
5
In the given reaction,
2X (g) + Y (g) 2Z (g) + 80 kcal
Which combination of pressure and temperature will give the highest yield of Z at equilibrium?
1000 atm and 200°C
500 atm and 500°C
1000 atm and 100°C
500 atm and 100°C
Which of the following compounds would have the smallest value for pKa?
CHF2CH2CH2COOH
CH3CH2CF2COOH
CH2FCHFCH2COOH
CH3CF2CH2COOH
A saturated solution of CaF2 is 2 × 10-4 mol/ L. Its solubility product constant is:
2.6 × 10-9
4 × 10-8
8 × 10-12
3.2 × 10-11