A chemical reaction is in equilibrium when
the reactants are completely transformed into products
the rate of forward reaction is equal to the rate of backward reaction
the formation of products is minimised
equal amount of reactants and products are present
For the following gaseous reaction, H2 + I2 2HI, the equilibrium constant
Kp > Kc
Kp< Kc
Kp= Kc
Kp= 1/Kc
According to Le-Chatelier's principle which of the following factors influence a chemical system?
Concentration only
Pressure only
Temperature only
Concentration, pressure and temperature
The pH of water decreases with?
increase in temperature
increase in pressure
decrease in temperature
decrease in pressure
If H+ concentration of fruit juice is 3.3 × 10-2, then its pH will be
4.8 basic
4.8 neutral
4.8 acidic
1.6 acidic
The correct order of the acidity of following acids is-
CH3COOH, HCOOH, Cl-CH2COOH, F-CH2COOH, (Cl2)CHCOOH
Cl2CHCOOH > F-CH2COOH > Cl-CH2COOH > HCOOH > CH3COOH
F-CH2COOH > Cl-CH2COOH > Cl2CHCOOH > HCOOH > CH3COOH
HCOOH > CH3COOH > Cl-CH2COOH > Cl2CHCOOH > F-CH2COOH
None of the above
A.
Cl2CHCOOH > F-CH2COOH > Cl-CH2COOH > HCOOH > CH3COOH
Group or atom attached with -COOH group shows positive inductive effect increases electron density on oxygen atom, which suppress the ionisation of H+, hence, acidic strength decreases.
Group or atom attached with -COOH group shows negative inductive effect decreases electron density on oxygen atom, which facilitate the ionisation of H+, hence acidic strength increases.
Sequence of group shows negative inductive effect-
-CHCl2 > -CH2F > -CH2Cl
-CH3 group shows positive inductive effect and -H does not show any effect.
Therefore, the correct order is-
Cl2CHCOOH > F-CH2COOH > Cl-CH2COOH > HCOOH > CH3COOH