The compounds A and B are mixed in equimolar proportion to form the products, A +B C+ D. At equilibrium, one third of A and B are consumed. The equilibrium constant for the reaction is
0.5
4.0
2.5
0.25
If, in the reaction N2O4 2NO2 ,x is that part of N2O4 which dissociates, then the number of molecules at equilibrium will be
1
3
(1 + x)
(1 + x)2
For the reaction
N2 (g) + O2 (g) 2NO (g), the value of Kc at 800°C is 0.1. When the equilibrium concentration of both the reactants is 0.5 mol, what is the value of Kp at the same temperature?
0.5
0.1
0.01
0.025
A buffer solution has equal volumes of 0.2 M NH4OH and 0.02 M NH4Cl. The pKb of the base is 5. The pH is
10
9
4
7
A precipitate of AgCl is formed when equal volumes of the following are mixed [Ksp for AgCl = 10-10]
10-4 M AgNO3 and 10-7 M HCl
10-5 M AgNO3 and 10-6 M HCl
10-5 M AgNO3 and 10-4 M HCl
10-6 M AgNO3 and 10-6 M HCl
C.
10-5 M AgNO3 and 10-4 M HCl
A precipitate of AgCl is formed when equal volumes of 10-5 M AgNO3 and 10-5 M HCl are mixed, because ionic product will be 10-9 which is greater than Ksp(10-10). For the precipitation of an electrolyte, it is necessary that the ionic product must exceed its solubility product.
4 moles each of SO2 and O2 gases are allowed to react to form SO3, in a closed vessel. At equilibrium 25% of O2 is used up. The total number of moles of all the gases at equilibrium is :
6.5
7.0
8.0
2.0
Solubility product of a salt AB is 1 x 10-8 M2 in a solution in which the concentration of A+ ions is 10M.The salt will precipitate when the concentration of B ions is kept :
between 10-8 M to 10-7 M
between 10-7 M to 10-8 M
>10-5 M
<10-8 M