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 Multiple Choice QuestionsMultiple Choice Questions

51.

By which of the following process hydrocarbons are found from petroleum?

  • Combustion

  • Fractional distillation

  • Addition

  • All of the above


52.

The false statement regarding alkane is

  • this does not perform polymerization reaction

  • this does not gives elimination reaction

  • it does not disappear the colour of dilute KMnO4 solution

  • it does not decolourise bromine water


53.

Which of the following aromatic compound gives sulphonation reaction very easily?

  • Chlorobenzene

  • Nitrobenzene

  • Toluene

  • Benzene


54.

Which of the following on combustion gives maximum energy?

  • Ethane

  • Propane

  • Methane 

  • Butane


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55.

C2H6 + CH3Cl Anhy. AlCl3 C6H5CH3 + HCl

The name of the above reaction is

  • Gattermann

  • Reimer-Tiemann

  • Friedel-Craft

  • Cannizzaro


56.

The tetraethyl lead mixed in petrol works as 

  • cooling agent

  • anti-knocking agent

  • bleaching agent

  • None of the above


57.

The number of alkenyl groups possible from C4H7 are

  • 7

  • 5

  • 3

  • 8


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58.

Among the following select the alkane that is expected to have lowest boiling point

  • hexane

  • 2-methylpentane

  • 3-methylpentane

  • 2,2-dimethylbutane


D.

2,2-dimethylbutane

As the number of carbon atom increases, the boiling points of alkane increases because van der waal's forces increases. However, branching results in decrease in boiling point due to decreased surface area which results in weaker van der waals' forces. Thus, order of boiling points of given alkanes is


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59.

'X' is an optically active alkane having lowest molecular mass, Predict the structure of the major product obtained on monochlorination of 'X'.


60.

Given: R = 8.314 JK-1 mol-1, the work done during combustion of 0.090 kg of ethane (molar mass = 30) at 300 K is

  • -18.7 kJ

  • 18.7 kJ

  • 6.234 kJ

  • -6.234 kJ


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